in neat (no solvent) (CH3)3SiNHTeF5 and PF5 stirred for 14 h at room temp.; products distilled under dynamic vac. through -30 (H2NTeF5), -78 (F3P=NTeF5) and -196°C ((CH3)3SiF and PF5) trap; elem. anal.;
参考文献
Hartl, Hans; Huppmann, Peter; Lentz, Dieter; Seppelt, Konrad
Inorganic Chemistry, 1983 , vol. 22, p. 2183 - 2187
in neat (no solvent) (CH3)3SiNHTeF5 filled into autoclave prior to addn. at -196°C SOF4 and mixt. slowly warmed to 65°C and stirred for 40 h; volatile materials pumped into -196°C cooled trap, vac. distillation through -25, -78 (O=SF2=NTeF5) and -196°C ((CH3)3SiF and SOF4) trap; elem. anal.;
参考文献
Hartl, Hans; Huppmann, Peter; Lentz, Dieter; Seppelt, Konrad
Inorganic Chemistry, 1983 , vol. 22, p. 2183 - 2187
nitronium hexafluorosilicate in dichloromethane T=-15 - -10°C; 1 h;
参考文献
Khodot, E. N.; Petrova, I. M.; Anikin, O. V.; Chlenov, I. E.
Russian Chemical Bulletin, 1995 , vol. 44, # 11 p. 2183 - 2185
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 11 p. 2276 - 2278
