反应条件
bis(η3-allyl-μ-chloropalladium(II)); (5S,2'R)-4,5-dihydro-2-(2'-diphenylphosphino-2'-phenylethyl)-5-tert-butyl-1,3-oxazole; tetrahexylammonium fluoride in acetonitrile Ambient temperatureother reactant: 2-cyclopentenyl acetate, other reagents: other chiral phosphine-oxazoline ligands/<Pd(η3-C3H5)Cl>2/nBu4NF or nHex4NF or nHex4NBr or TBAOAc or KOAc, NaH presence, other solvents: CH2Cl2, C6H6, THF, other temperature; MechanismProduct distribution;
参考文献
Gilbertson, Scott R.; Chang, Cheng-Wei T.
Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8424 - 8431