(1-辛基)三苯基溴化磷合成路线 （共 14 条）
反应条件
in chlorobenzene 48 h; Heating;
参考文献
Zhu, Yingdong; Soroka, Dominique N.; Sang, Shengmin
Journal of Agricultural and Food Chemistry, 2012 , vol. 60, # 35 p. 8624 - 8631
反应条件
triphenylphosphine in toluene T=110°C; 48 h; Inert atmosphere;
参考文献
Maegawa, Tomohiro; Koutani, Yasuyuki; Otake, Kazuki; Fujioka, Hiromichi
Journal of Organic Chemistry, 2013 , vol. 78, # 7 p. 3384 - 3390
反应条件
in hexane Ambient temperature;
参考文献
Turos, Edward; Boy, Kenneth; Ren, Xiao-Feng
Journal of Organic Chemistry, 1992 , vol. 57, # 24 p. 6667 - 6669
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane 1.2: 56.8 percent / tetrahydrofuran; hexane 2.1: 80.6 percent / H2 / Pd/C / ethanol / 20 °C View Scheme
参考文献
Tyman, John H.P.; Mehet, Satinderjit K.
Chemistry and Physics of Lipids, 2003 , vol. 126, # 2 p. 177 - 199
反应条件
n-butyllithium; hexane multistep reaction: 1.) THF, 0 deg C, then room t., 2 h, 2.) THF, -78 deg C to room t., 30 min; reactions under var. conditions and var. with reagents; Product distribution;
参考文献
Pelter; Smith; Elgendy
Tetrahedron, 1993 , vol. 49, # 32 p. 7119 - 7132
反应条件
n-butyllithium; hexane
1.) THF, 0 deg C, then room t., 2 h, 2.) THF, -78 deg C to room t., 3 min; Yield given. Multistep reaction;
参考文献
Pelter, Andrew; Smith, Keith; Elgendy, Said M. A.; Rowlands, Martin
Tetrahedron, 1993 , vol. 49, # 32 p. 7104 - 7118
反应条件
1: 850 mg / diethyl ether / 60 h
2: 64 percent / lithium triethylborohydride / tetrahydrofuran / 0.25 h / 20 °C
3: 61 percent / H2 / platinum oxide / 18 h / 150 °C / ethyl palmitate
View Scheme
参考文献
Igner, Eva; Paynter, Oliver I.; Simmonds, Derek J.; Whiting, Mark C.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 2447 - 2454
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane
1.2: 56.8 percent / tetrahydrofuran; hexane
2.1: 80.6 percent / H2 / Pd/C / ethanol / 20 °C
3.1: ethylmagnesium bromide / diethyl ether / 20 °C
3.2: 42 percent / hexamethylphosphoramide / benzene / Heating
View Scheme
参考文献
Tyman, John H.P.; Mehet, Satinderjit K.
Chemistry and Physics of Lipids, 2003 , vol. 126, # 2 p. 177 - 199
反应条件
n-butyllithium in tetrahydrofuran; hexane
15 h; Ambient temperature;
参考文献
Shiozaki, Masao; Kobayashi, Yoshiyuki
Tetrahedron: Asymmetry, 1992 , vol. 3, # 3 p. 451 - 458
反应条件
n-butyllithium; hexane
multistep reaction: 1.) THF, 0 deg C, then room t., 2 h, 2.) THF, -78 deg C to room t., 30 min; reactions under var. conditions and var. with reagents; Product distribution;
参考文献
Pelter; Smith; Elgendy
Tetrahedron, 1993 , vol. 49, # 32 p. 7119 - 7132
