C6F5NH3(1+)*OTf(1-) T=90°C; Ritter reaction; 2 h; Neat (no solvent); chemoselective reaction;

hydrogen; rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate; (Sa)-monophos in dichloromethane T=20°C; P=11251.1 Torr; 20 h;

暂无反应条件数据

sodium azide; ammonium cerium(IV) nitrate T=0°C; Ritter amidation; 0.5 h;

tetrafluoroboric acid diethyl ether complex T=23°C; Ritter reaction; 7 h; Neat (no solvent);

acetic anhydride

bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; C55H31BF22N2O2P(1-)*C16H36N(1+); hydrogen; triphenylphosphine in ethyl acetate T=20°C; P=15001.5 Torr; 4 h; Inert atmosphereSchlenk technique; Reagent/catalystSolvent; enantioselective reaction;

1: acetic acid; iron; chloro-trimethyl-silane / toluene / 4 h / 70 °C / |Inert atmosphere; |Schlenk technique 2: C55H31BF22N2O2P(1-)*C16H36N(1+); bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; triphenylphosphine / ethyl acetate / 4 h / 20 °C / 15001.5 Torr / |Inert atmosphere; |Schlenk technique View Scheme

1: sodium acetate; hydroxylamine hydrochloride / methanol / 17.5 h / 20 °C / |Inert atmosphere; |Schlenk technique 2: acetic acid; iron; chloro-trimethyl-silane / toluene / 4 h / 70 °C / |Inert atmosphere; |Schlenk technique 3: C55H31BF22N2O2P(1-)*C16H36N(1+); bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; hydrogen; triphenylphosphine / ethyl acetate / 4 h / 20 °C / 15001.5 Torr / |Inert atmosphere; |Schlenk technique View Scheme

lithium perchlorate; Ru(CH3CN)3Cl3 in acetonitrile Catalytic oxidation; 4 h; Electrolysis; Product distributionKinetics; Further Variations:ReagentsReaction partnersCatalystsreaction time;