(S)-(+)-3-甲基-1-戊醇合成路线 （共 30 条）
反应条件
1: aq. LiCl / dimethylformamide / 160 °C 2: DIBAL-H / hexane; diethyl ether / 3 h / -78 °C View Scheme
参考文献
Schuppan, Julia; Minnaard, Adriaan J.; Feringa, Ben L.
Chemical Communications, 2004 , # 7 p. 792 - 793
反应条件
2: copper-chromium oxide / 250 °C / 147102 - 202265 Torr View Scheme
参考文献
Bowden; Adkins
Journal of the American Chemical Society, 1934 , vol. 56, p. 689
反应条件
sulfuric acid in ethanol
参考文献
Salvadori,P.; Lardicci,L.
Gazzetta Chimica Italiana, 1964 , vol. 94, p. 1205 - 1220
反应条件
sodium tetrahydroborate
参考文献
Salvadori,P. et al.
Tetrahedron Letters, 1977 , p. 195 - 198
反应条件
1: Ph3P / CH2Cl2 / 2 h 2: 1.) O3/O2, 2.) LiAlH4 / 1.) CH2Cl2/pentane, -30 deg C, 4 h, 2.) Et2O View Scheme
参考文献
Marcacci, Fabrizio; Giacomelli, Giampaolo; Menicagli, Rita
Gazzetta Chimica Italiana, 1980 , vol. 110, # 2/3 p. 195 - 200
反应条件
(i) SOCl2, (ii) /BRN= 1900390/, (iii) LiAlH4; Multistep reaction;
参考文献
Smolinsky,G.; Feuer,B.I.
Journal of the American Chemical Society, 1964 , vol. 86, p. 3085 - 3088
反应条件
1: SOCl2 2: (i) Mg, (ii) /BRN= 1209228/ View Scheme
参考文献
Nozakura,S. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1673 - 1678
反应条件
lithium aluminium tetrahydride; oxygen; ozone 1.) CH2Cl2/pentane, -30 deg C, 4 h, 2.) Et2O; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Marcacci, Fabrizio; Giacomelli, Giampaolo; Menicagli, Rita
Gazzetta Chimica Italiana, 1980 , vol. 110, # 2/3 p. 195 - 200
反应条件
2: (i) O3, (ii) LiAlH4 View Scheme
参考文献
Salvadori,P. et al.
Tetrahedron Letters, 1977 , p. 195 - 198
反应条件
(i) Mg, (ii) /BRN= 1209228/; Multistep reaction;
参考文献
Nozakura,S. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1673 - 1678
