1,1,1,2-四氟丙烷合成路线 （共 23 条）
反应条件
potassium hydroxide; anhydrous potassium sulfate; hydrogen; 5-palladium/activated carbon in water
T=1 - 2°C; P=1200.12 Torr; 10.4 h;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: WO2009/35130 A2, 2009 ;
Location in patent: Page/Page column 11-12 ;
反应条件
anhydrous potassium sulfate; hydrogen; potassium hydroxide; 5 Pd(II)/C(eggshell)
T=1 - 8°C; 27 h; Autoclave;
参考文献
DAIKIN INDUSTRIES, LTD.; NOSE, Masatoshi; SUZUKI, Atsushi; SUGIYAMA, Akinari
Patent: WO2010/13576 A1, 2010 ;
Location in patent: Page/Page column 8-9 ;
反应条件
hydrogen; 0.5 Pd/C
T=85°C; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/30440 A2, 2008 ;
Location in patent: Page/Page column 19 ;
反应条件
hydrogen; 5 Pd/C
T=225°C; Flow reactor;
参考文献
E. I. du Pont de Nemours and Company; KNAPP, Jeffrey, P.
Patent: WO2011/53449 A1, 2011 ;
Location in patent: Page/Page column 15-16 ;
反应条件
hydrogen; potassium acetate; palladium 10 on activated carbon in ethanol
T=65°C; P=7757.43 Torr; 16 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2008/27251 A1, 2008 ;
Location in patent: Page/Page column 3 ;
反应条件
hydrogen; potassium acetate; palladium 10 on activated carbon in ethanol
T=120°C; P=7757.43 Torr; 16 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2008/27251 A1, 2008 ;
Location in patent: Page/Page column 3 ;
反应条件
hydrogen; 1 palladium on alumina
T=250°C; 0.00833333 h; Flow reactor;
参考文献
E. I. du Pont de Nemours and Company; KNAPP, Jeffrey, P.
Patent: WO2011/53449 A1, 2011 ;
Location in patent: Page/Page column 15 ;
反应条件
hydrogen; 0.5 Pd/C
T=175 - 225°C; Gas phase;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37743 A1, 2005 ;
Location in patent: Page/Page column 16; 19 ;
反应条件
hydrogen; 1 palladium on alumina
T=175°C; 0.00833333 h; Flow reactor;
参考文献
E. I. du Pont de Nemours and Company; KNAPP, Jeffrey, P.
Patent: WO2011/53449 A1, 2011 ;
Location in patent: Page/Page column 15 ;
反应条件
hydrogen; fluorided Pt/Al2O3
T=250°C; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/54778 A2, 2008 ;
Location in patent: Page/Page column 14-15 ;
