3-硝基-9H-芴-9-酮合成路线 （共 22 条）
反应条件
triethylsilane in trifluoroacetic acid 48 h; Ambient temperature;
参考文献
Synthesis, , # 3 p. 184 - 188
反应条件
1: N2H4*H2O, NaOH, HOCH2CH2OH / Heating 2: aq. H2O2, maleic anhydride / CH2Cl2 / Heating View Scheme
参考文献
Yost,Y.; Gutmann,H.R.
Journal of the Chemical Society [Section] C: Organic, 1969 , p. 345 - 350
参考文献
Iihama, T.; Fu, J.-m.; Bourguignon, M.; Snieckus, V.
Synthesis, 1989 , # 3 p. 184 - 188
反应条件
1: With trifluoroacetic anhydride
T=100°C; 2 h;
2: With hydrogenchloride in water
T=100°C; 2 h;
参考文献
Chinnagolla, Ravi Kiran; Jeganmohan, Masilamani
Organic Letters, 2012 , vol. 14, # 20 p. 5246 - 5249,4
反应条件
1: 2.) 2 M aq. Na2CO3 / 1.) Pd(PPh3)4 / 1.) EtOH, DME, 10 min, 2.) reflux, 20 h
2: 76 percent / NBS / benzoyl peroxide / CCl4 / 36 h / Heating
3: AgNO3 / dioxane; H2O / 18 h / Ambient temperature
4: aq. KOH / dioxane / 20 h / Ambient temperature
5: 98 percent / aq. KMnO4 / acetone / 4 h / Ambient temperature
6: 88 percent / polyphosphoric acid / 5 h / 160 °C
View Scheme
参考文献
Iihama, T.; Fu, J.-m.; Bourguignon, M.; Snieckus, V.
Synthesis, 1989 , # 3 p. 184 - 188
反应条件
1: 2.) 2 M aq. Na2CO3 / 1.) Pd(PPh3)4 / 1.) EtOH, DME, 10 min, 2.) reflux, 20 h
2: 76 percent / NBS / benzoyl peroxide / CCl4 / 36 h / Heating
3: AgNO3 / dioxane; H2O / 18 h / Ambient temperature
4: aq. KOH / dioxane / 20 h / Ambient temperature
5: 98 percent / aq. KMnO4 / acetone / 4 h / Ambient temperature
6: 88 percent / polyphosphoric acid / 5 h / 160 °C
View Scheme
参考文献
Iihama, T.; Fu, J.-m.; Bourguignon, M.; Snieckus, V.
Synthesis, 1989 , # 3 p. 184 - 188
反应条件
1: 76 percent / NBS / benzoyl peroxide / CCl4 / 36 h / Heating
2: AgNO3 / dioxane; H2O / 18 h / Ambient temperature
3: aq. KOH / dioxane / 20 h / Ambient temperature
4: 98 percent / aq. KMnO4 / acetone / 4 h / Ambient temperature
5: 88 percent / polyphosphoric acid / 5 h / 160 °C
View Scheme
参考文献
Iihama, T.; Fu, J.-m.; Bourguignon, M.; Snieckus, V.
Synthesis, 1989 , # 3 p. 184 - 188
反应条件
aluminum oxide in benzene
参考文献
Pan,H.-L. et al.
Synthesis, 1975 , p. 716
反应条件
1: 98 percent / aq. KMnO4 / acetone / 4 h / Ambient temperature
2: 88 percent / polyphosphoric acid / 5 h / 160 °C
View Scheme
参考文献
Iihama, T.; Fu, J.-m.; Bourguignon, M.; Snieckus, V.
Synthesis, 1989 , # 3 p. 184 - 188
反应条件
1: AgNO3 / dioxane; H2O / 18 h / Ambient temperature
2: aq. KOH / dioxane / 20 h / Ambient temperature
3: 98 percent / aq. KMnO4 / acetone / 4 h / Ambient temperature
4: 88 percent / polyphosphoric acid / 5 h / 160 °C
View Scheme
参考文献
Iihama, T.; Fu, J.-m.; Bourguignon, M.; Snieckus, V.
Synthesis, 1989 , # 3 p. 184 - 188
