1,12-二乙酰氧基十二烷合成路线 （共 18 条）
反应条件
sulfuric acid T=50°C; 1 h;
参考文献
Zakharkin, L. I.; Guseva, V. V.
Chemistry of Natural Compounds, 1984 , vol. 20, # 6 p. 733 - 736
Khimiya Prirodnykh Soedinenii, 1984 , vol. 20, # 6 p. 776 - 779
参考文献
Sheepwash, Erin E.; Rowntree, Paul A.; Schwan, Adrian L.
Journal of Labelled Compounds and Radiopharmaceuticals, 2008 , vol. 51, # 12 p. 391 - 398
反应条件
1: 71 percent / stearic acid, palmitic acid / 350 °C / 260 Torr 2: 93 percent / H2SO4 / 1 h / 50 °C View Scheme
参考文献
Chuit
Helvetica Chimica Acta, 1926 , vol. 9, p. 265
反应条件
1: HBr 2: acetic acid View Scheme
参考文献
Chuit
Helvetica Chimica Acta, 1926 , vol. 9, p. 265
Full Text Show Details
Lespieau
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1928 , vol. 187, p. 606
Bulletin de la Societe Chimique de France, 1928 , vol. <4>43, p. 1190
参考文献
Chuit
Helvetica Chimica Acta, 1926 , vol. 9, p. 265
Full Text Show Details
Lespieau
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1928 , vol. 187, p. 606
Bulletin de la Societe Chimique de France, 1928 , vol. <4>43, p. 1190
反应条件
1: magnesium; diethyl ether / durch Einw. von Chlordimethylaether auf das Reaktionsprodukt anfangs unter Kuehlung, spaeter auf dem Wasserbad 2: HBr 3: acetic acid View Scheme
参考文献
Lespieau
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1928 , vol. 187, p. 606
Bulletin de la Societe Chimique de France, 1928 , vol. <4>43, p. 1190
反应条件
in ethyl acetate T=450 - 470°C; quartz tube packed with glass;
参考文献
Chemistry of Natural Compounds, , vol. 20, # 6 p. 733 - 736
Khimiya Prirodnykh Soedinenii, , vol. 20, # 6 p. 776 - 779
反应条件
1: 65 percent / ethyl acetate / 450 - 470 °C / quartz tube packed with glass 2: 98 percent / KOH / methanol; H2O / 8 h / Heating 3: 90 percent / bromine / CCl4 / 0.5 h / 20 °C 4: 75 percent / 18-crown-6-ether, KOH / petroleum ether / 10 h / 90 - 110 °C 5: 1) lithium amide / 1) THF, 30-35 deg C, 0.5 h; 2) HMPTA, 20 deg C, 2 h. 6: hydrogen, quinoline / 5percent Pd/BaSO4 / hexane / 20 °C View Scheme
参考文献
Zakharkin, L. I.; Guseva, V. V.
Chemistry of Natural Compounds, 1984 , vol. 20, # 6 p. 733 - 736
Khimiya Prirodnykh Soedinenii, 1984 , vol. 20, # 6 p. 776 - 779
反应条件
methanol; potassium hydroxide T=60°C; 1.5 h;
参考文献
Sheepwash, Erin E.; Rowntree, Paul A.; Schwan, Adrian L.
Journal of Labelled Compounds and Radiopharmaceuticals, 2008 , vol. 51, # 12 p. 391 - 398
反应条件
1: 65 percent / ethyl acetate / 450 - 470 °C / quartz tube packed with glass 2: 98 percent / KOH / methanol; H2O / 8 h / Heating View Scheme
参考文献
Zakharkin, L. I.; Guseva, V. V.
Chemistry of Natural Compounds, 1984 , vol. 20, # 6 p. 733 - 736
Khimiya Prirodnykh Soedinenii, 1984 , vol. 20, # 6 p. 776 - 779
