反应条件
1: cyclopenta-1,3-diene With n-butyl-magnesium bromide in tert-butyl methyl ether
Inert atmosphere;
2: cycloheptyl bromide With copper(II) bis(trifluoromethanesulfonate) in tert-butyl methyl ether; di-isopropyl ether
6 h; Inert atmosphereReflux;
3: With platinum(IV) oxide; hydrogen in acetic acid
P=750.075 Torr; 12 h; RefluxInert atmosphere;
参考文献
Sai, Masahiro; Someya, Hidenori; Yorimitsu, Hideki; Oshima, Koichiro
Organic Letters, 2008 , vol. 10, # 12 p. 2545 - 2547
