2-羟基-1,2,2-三苯乙酮合成路线 （共 78 条）
反应条件
1: C11H13PolS2 With n-butyllithium in tetrahydrofuran
T=-35°C; 2 h; solid phase reaction;
2: benzophenone in tetrahydrofuran; Petroleum ether
T=-10°C; solid phase reaction;
3: With mercury(II) perchlorate; water; calcium carbonate in tetrahydrofuran
参考文献
Bertini, Vincenzo; Lucchesini, Francesco; Pocci, Marco; Alfei, Silvana; Idini, Barbara
Synlett, 2008 , # 8 p. 1141 - 1144
反应条件
iodine; magnesium
2.) THF, 245 K; Multistep reaction;
参考文献
Wada, Shin-Ichi; Matsushita, Yoshihisa; Obi, Kinichi
Journal of Physical Chemistry A, 1997 , vol. 101, # 13 p. 2423 - 2428
反应条件
1: Bromure de phenyl magnesium With tributylphosphine in tetrahydrofuran
T=20°C; 0.333333 h;
2: oxalyl dichloride in tetrahydrofuran
T=-40°C; 0.333333 h;
参考文献
Maeda; Hino; Yamauchi; Ohmori
Chemical and Pharmaceutical Bulletin, 2000 , vol. 48, # 8 p. 1196 - 1199
反应条件
sodium acetate
2 h; Ambient temperature;
参考文献
Olah, George A.; Wu, An-hsiang
Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2531 - 2534
反应条件
in tetrahydrofuran
T=25°C; 48 h; Title compound not separated from byproducts;
参考文献
Maruyama,K.; Katagiri,T.
Journal of the American Chemical Society, 1986 , vol. 108, p. 6263
反应条件
nitric acid; acetic acid
参考文献
Biltz
Chemische Berichte, 1899 , vol. 32, p. 655
反应条件
silver trifluoroacetate
1.) CH2Cl2, -58 deg C, 50 min; 2.) water; further silver salt catalysts; different time and temperatures; Product distribution;
参考文献
Ohwada,T.; Shudo,K.
Journal of the American Chemical Society, 1988 , vol. 110, p. 1862
反应条件
sulfuric acid; acetone
参考文献
Stevens; DeYoung
Journal of the American Chemical Society, 1954 , vol. 76, p. 718
反应条件
oxygen in dichloromethane
T=25°C; 24 h; Further byproducts given;
参考文献
Yamamoto, Hiroshi; Miura, Masahiro; Nojima, Masatomo; Kusabayashi, Shigekazu
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 173 - 182
反应条件
carbon monoxide; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
High Pressure; 0.5 mmol PhCOCl, 1 mmol Ph2Zn, 2 mmol MgClBr, 0.05 mmol Pd complex, 20 ml THF, CO 30 atm, stirred at 25°C for 16 h; GC-MS, GC;
参考文献
Yamashita, Hiroshi; Kobayashi, Toshi-aki; Sakakura, Toshiyasu; Tanaka, Masato
Journal of Organometallic Chemistry, 1988 , vol. 356, p. 125 - 132
