乙烯基1,1,2,2,3,3,4,4,4-九氟-1-丁烷磺酸酯合成路线 (共 7 条)
反应条件
1: 4-iodobenzoic acid ethyl ester With isopropylmagnesium chloride in tetrahydrofuran; ethylene glycol dimethyl ether T=-20°C; 2: in tetrahydrofuran; ethylene glycol dimethyl ether 0.333333 h; 3: ethenyl nonaflate With iron (III) acetylacetonate in tetrahydrofuran; ethylene glycol dimethyl ether T=20°C; 0.5 h;
参考文献
Dunet, Guillaume; Knochel, Paul
Synlett, 2006 , # 3 p. 407 - 410
反应条件
1: .alpha.-naphthylmagnesiumchloride With CuCN*2LiCl in tetrahydrofuran T=-20°C; 2: ethenyl nonaflate With iron (III) acetylacetonate in tetrahydrofuran; ethylene glycol dimethyl ether T=20°C;
参考文献
Dunet, Guillaume; Knochel, Paul
Synlett, 2006 , # 3 p. 407 - 410
反应条件
potassium acetate; potassium carbonate; palladium diacetate in N,N-dimethyl-formamide T=70°C; Heck reaction; 7 h;
参考文献
European Journal of Organic Chemistry, , # 22 p. 4189 - 4194
反应条件
1: C6H4BrClMg With CuCN*2LiCl in tetrahydrofuran T=-20°C; 2: ethenyl nonaflate With iron (III) acetylacetonate in tetrahydrofuran; ethylene glycol dimethyl ether T=20°C;
参考文献
Dunet, Guillaume; Knochel, Paul
Synlett, 2006 , # 3 p. 407 - 410
反应条件
1: tetrahydrofuran With n-butyllithium in hexane
T=35°C; 3 h;
2: nonafluoro-n-butanesulfonyl fluoride in tetrahydrofuran; hexane
T=-78 - 20°C; 16 h; Further stages.;
参考文献
Lyapkalo, Ilya M.; Webel, Matthias; Reissig, Hans-Ulrich
European Journal of Organic Chemistry, 2001 , # 22 p. 4189 - 4194
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
T=20°C; 16 h;
参考文献
Lyapkalo, Ilya M.; Webel, Matthias; Reissig, Hans-Ulrich
European Journal of Organic Chemistry, 2001 , # 22 p. 4189 - 4194
反应条件
1: 1-n-decyne; ethylmagnesium bromide in tetrahydrofuran
T=20°C; 0.5 h;
2: ethenyl nonaflate With Co(acetylacetonate)3 in tetrahydrofuran
T=20°C; 2 h; Further stages.;
参考文献
Shirakawa, Eiji; Sato, Takahiro; Imazaki, Yusuke; Kimura, Takahiro; Hayashi, Tamio
Chemical Communications, 2007 , # 43 p. 4513 - 4515