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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
42447-90-5
合成路线
(共 8 条)
42447-90-5
→
反应条件
34472-48-5
1-丙-2-亚基茚
反应条件
4-nitro-phenol; sodium 4-nitrophenolate in methanol T=30°C; kinetic isotope effect, influence of p-NO2PhOH concentration; Rate constant;
参考文献
Thibblin, Alf
Journal of the American Chemical Society, 1983 , vol. 105, # 4 p. 853 - 858
42447-90-5
→
反应条件
63927-10-6
+
64391-30-6
+
34472-48-5
1-丙-2-亚基茚
+
118719-21-4
+
102101-28-0
反应条件
sodium perchlorate; acetonitrile T=35°C; experiment with deuteriated educt; Rate constantProduct distribution;
参考文献
Thibblin, Alf
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 321 - 326
42447-90-5
→
反应条件
63927-10-6
+
64391-30-6
+
34472-48-5
1-丙-2-亚基茚
反应条件
sodium azide; sodium perchlorate; acetonitrile T=35°C; product distribution; Rate constantEquilibrium constantMechanism;
参考文献
Thibblin, Alf
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 313 - 320
42271-88-5
→
反应条件
42447-90-5
反应条件
4-nitro-phenol; sodium 4-nitrophenolate in methanol T=30°C; kinetic isotope effect, influence of p-NO2PhOH concentration, further bases; Rate constant;
参考文献
Thibblin, Alf
Journal of the American Chemical Society, 1983 , vol. 105, # 4 p. 853 - 858
64391-30-6
+
108-24-7
乙酸酐
→
反应条件
42447-90-5
+
102101-28-0
反应条件
zinc(II) chloride 0.0166667 h;
参考文献
Thibblin, Alf
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 313 - 320
102101-28-0
→
反应条件
63927-10-6
+
64391-30-6
+
34472-48-5
1-丙-2-亚基茚
+
42447-90-5
+
118719-21-4
反应条件
sodium perchlorate; acetonitrile T=35°C; Product distributionMechanismRate constant;
参考文献
Thibblin, Alf
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 313 - 320
42447-90-5
→
反应条件
63927-10-6
+
64391-30-6
+
34472-48-5
1-丙-2-亚基茚
+
118719-21-4
+
102101-28-0
反应条件
sodium perchlorate; acetonitrile T=35°C; experiment with deuteriated educt; Rate constantProduct distribution;
参考文献
Thibblin, Alf
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 321 - 326
42447-90-5
→
反应条件
63927-10-6
+
64391-30-6
+
34472-48-5
1-丙-2-亚基茚
反应条件
sodium azide; sodium perchlorate; acetonitrile T=35°C; product distribution; Rate constantEquilibrium constantMechanism;
参考文献
Thibblin, Alf
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 313 - 320