6,7-去氢-17alpha-乙酰氧基黄体酮合成路线 (共 3 条)
反应条件
1: With chloranil in tert-butyl alcohol T=80°C; 5 h; 2: With sodium carbonate in water; tert-butyl alcohol
参考文献
Boehringer Ingelheim International GmbH
Patent: EP1359154 A1, 2003 ;
Location in patent: Page/Page column title page; 4; 17; 25; 30; 32 ;
反应条件
tetramethyl-ammonium fluoride in acetonitrile T=60°C; 2 h;
参考文献
Carlon, F. Emilie; Draper, Richard W.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 11 p. 2793 - 2799
反应条件
acetic anhydride in tetrachloromethane
参考文献
Yasuda,K.
Chemical and Pharmaceutical Bulletin, 1963 , vol. 11, p. 1167 - 1174