您好，欢迎来到魔法化学网！
合作交流
|
服务时间(9:30-18:00)
百科
百科
▼
百科
资讯
搜索
结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
首页
化合物百科
价格行情
资讯
化工导航
实验室工具
搜索
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
42542-99-4
合成路线
（共 25 条）
108-86-1
溴代苯
+
874-14-6
1,3-二甲基脲嘧啶
→
反应条件
42542-99-4
+
55377-22-5
反应条件
palladium diacetate; potassium carbonate; triphenylphosphine; 2,2,2-trimethylacetic acid in N,N-dimethyl-formamide T=130°C; 12 h; Inert atmosphere; regioselective reaction;
参考文献
Kim, Ko Hoon; Lee, Hyun Seung; Kim, Jae Nyoung
Tetrahedron Letters, 2011 , vol. 52, # 47 p. 6228 - 6233
874-14-6
1,3-二甲基脲嘧啶
+
13471-35-7
B-苯基-硼酸二甲酯
→
反应条件
42542-99-4
反应条件
1,10-phenanthroline; oxygen; palladium diacetate in N,N-dimethyl-formamide T=90°C; Heck Reaction; 16 h; regioselective reaction;
参考文献
Mondal, Biplab; Hazra, Somjit; Roy
Tetrahedron Letters, 2014 , vol. 55, # 5 p. 1077 - 1081
874-14-6
1,3-二甲基脲嘧啶
+
591-50-4
碘苯
→
反应条件
42542-99-4
反应条件
copper(I) bromide; lithium tert-butylate in N,N-dimethyl-formamide 1 h; Reflux; Reagent/catalystSolventTemperature; regioselective reaction;
参考文献
Cheng, Chien; Shih, Yu-Chiao; Chen, Hui-Ting; Chien, Tun-Cheng
Tetrahedron, 2013 , vol. 69, # 4 p. 1387 - 1396
7033-39-8
5-溴-1,3-二甲基尿嘧啶
+
591-50-4
碘苯
→
反应条件
42542-99-4
+
98854-09-2
5-溴-1,3-二甲基-6-苯基尿嘧啶
反应条件
copper(I) bromide; lithium tert-butylate in N,N-dimethyl-formamide 1 h; Reflux; regioselective reaction;
参考文献
Cheng, Chien; Shih, Yu-Chiao; Chen, Hui-Ting; Chien, Tun-Cheng
Tetrahedron, 2013 , vol. 69, # 4 p. 1387 - 1396
874-14-6
1,3-二甲基脲嘧啶
+
98-80-6
苯硼酸
→
反应条件
42542-99-4
反应条件
1,10-phenanthroline; oxygen; palladium diacetate in N,N-dimethyl-formamide T=90°C; Heck Reaction; 16 h; Catalytic behavior; SolventReagent/catalystTemperatureTime; regioselective reaction;
参考文献
Mondal, Biplab; Hazra, Somjit; Roy
Tetrahedron Letters, 2014 , vol. 55, # 5 p. 1077 - 1081
874-14-6
1,3-二甲基脲嘧啶
+
591-50-4
碘苯
→
反应条件
42542-99-4
+
55377-22-5
反应条件
palladium diacetate; caesium carbonate; RF-PPh3 in N,N-dimethyl-formamide T=160°C; 50 h; Inert atmosphere; regioselective reaction;
参考文献
Cernova, Miroslava; Pohl, Radek; Hocek, Michal
European Journal of Organic Chemistry, 2009 , # 22 p. 3698 - 3701
874-14-6
1,3-二甲基脲嘧啶
+
696-62-8
4-碘苯甲醚
→
反应条件
42542-99-4
反应条件
copper(l) iodide; caesium carbonate in N,N-dimethyl-formamide T=160°C; 50 h; Inert atmosphere; regioselective reaction;
参考文献
Cernova, Miroslava; Pohl, Radek; Hocek, Michal
European Journal of Organic Chemistry, 2009 , # 22 p. 3698 - 3701
874-14-6
1,3-二甲基脲嘧啶
+
591-50-4
碘苯
+
1420467-10-2
→
反应条件
42542-99-4
+
1420467-11-3
反应条件
copper(I) bromide; lithium tert-butylate in N,N-dimethyl-formamide 1 h; Reflux; Reagent/catalystSolventTemperature; Overall yield = 87 percent; regioselective reaction;
参考文献
Cheng, Chien; Shih, Yu-Chiao; Chen, Hui-Ting; Chien, Tun-Cheng
Tetrahedron, 2013 , vol. 69, # 4 p. 1387 - 1396
6972-27-6
6-氯-1,3-二甲基脲嘧啶
+
24388-23-6
苯硼酸频哪醇酯
→
反应条件
42542-99-4
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; water Suzuki-Miyaura coupling; 16 h; Reflux;
参考文献
Shih, Yu-Chiao; Chien, Tun-Cheng
Tetrahedron, 2011 , vol. 67, # 21 p. 3915 - 3923
6972-27-6
6-氯-1,3-二甲基脲嘧啶
+
960-16-7
三丁基苯基锡
→
反应条件
42542-99-4
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; water Stille coupling; 16 h; Reflux;
参考文献
Shih, Yu-Chiao; Chien, Tun-Cheng
Tetrahedron, 2011 , vol. 67, # 21 p. 3915 - 3923
1
2
3
下一页
末页
到第
页
确定
