1,1-二氟-1,2-丙二烯合成路线 （共 18 条）
反应条件
T=100°C; 3 h; Yield given. Yields of byproduct given;
参考文献
Tetrahedron Letters, , vol. 28, # 14 p. 1491 - 1492
反应条件
1: With n-butyllithium in diethyl ether
T=-78°C; 0.25 h;
2: With methanol in diethyl ether
T=-78°C;
参考文献
Nadano, Ryo; Ichikawa, Junji
Synthesis, 2006 , # 1 art. no. F10205SS, p. 128 - 132
反应条件
1: With carbon
T=500°C; 5 h;
2: With hydrogenchloride
T=50 - 400°C; 3 h;
3: Solkane® 365mfc T=300 - 450°C; Product distribution / selectivity;
参考文献
CENTRAL GLASS COMPANY, LIMITED
Patent: WO2004/96737 A2, 2004 ;
Location in patent: Page 22-23; 24 ;
反应条件
n-butyllithium in hexane
1.) -80 deg C, 25 min; 2.) allowed to -30 deg C; 3.) allowed to 28 deg C;
参考文献
Dolbier, William R.; Burkholder, Conrad R.; Piedrahita, Carlos A.
Journal of Fluorine Chemistry, 1982 , vol. 20, p. 637 - 648
参考文献
Knoth,W.H.; Coffman,D.D.
Journal of the American Chemical Society, 1960 , vol. 82, p. 3873 - 3875
反应条件
T=832 - 857°C; P=0.7 - 1.3 Torr;
参考文献
Knoth,W.H.; Coffman,D.D.
Journal of the American Chemical Society, 1960 , vol. 82, p. 3873 - 3875
反应条件
n-butyllithium in ethylene glycol dimethyl ether
1.) -78 deg C; 2.) 0 deg C;;
参考文献
Shi, Guoqiang; Xu, Yuanyao
Journal of Fluorine Chemistry, 1989 , vol. 44, p. 161 - 166
参考文献
Blomquist; Longone
Journal of the American Chemical Society, 1957 , vol. 79, p. 4981
参考文献
Dolbier, William R.; Sellers, Simon F.; Al-Sader, Basil H.; Smart, Bruce E.
Journal of the American Chemical Society, 1980 , vol. 102, # 16 p. 5398 - 5399
参考文献
Drakesmith,F.G. et al.
Journal of Organic Chemistry, 1968 , vol. 33, # 1 p. 280 - 285
