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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
(R)-3-苯基哌啶
合成路线
（共 11 条）
430461-53-3
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
hydrogen; palladium dihydroxide in ethyl acetate T=25°C; 25 h;
参考文献
Amat, Mercedes; Canto, Margalida; Llor, Nuria; Escolano, Carmen; Molins, Elies; Espinosa, Enrique; Bosch, Joan
Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5343 - 5351
56613-80-0
D-苯甘氨醇
+
343947-52-4
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1: in toluene 14 h; Heating; 2: With lithium aluminium tetrahydride in tetrahydrofuran 3: With hydrogen; palladium dihydroxide in ethyl acetate
参考文献
Amat, Mercedes; Canto, Margalida; Llor, Nuria; Ponzo, Viviana; Perez, Maria; Bosch, Joan
Angewandte Chemie - International Edition, 2002 , vol. 41, # 2 p. 335 - 338
332-15-0
1-[(E)-2-苯乙烯基]哌啶
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1.1: acetonitrile / 36 h / Heating 1.2: 45 percent / aqueous acetic acid / acetonitrile / 8 h / Heating 2.1: 49 percent / toluene / 24 h / Heating 3.1: 72 percent / LiAlH4 / tetrahydrofuran / 1 h / 20 °C 4.1: 75 percent / hydrogen / Pd(OH)2/C / ethyl acetate / 25 h / 25 °C View Scheme
参考文献
Amat, Mercedes; Canto, Margalida; Llor, Nuria; Escolano, Carmen; Molins, Elies; Espinosa, Enrique; Bosch, Joan
Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5343 - 5351
122-78-1
苯乙醛
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1.1: 78 percent / Na2CO3 / 3 h / 0 °C 2.1: acetonitrile / 36 h / Heating 2.2: 45 percent / aqueous acetic acid / acetonitrile / 8 h / Heating 3.1: 49 percent / toluene / 24 h / Heating 4.1: 72 percent / LiAlH4 / tetrahydrofuran / 1 h / 20 °C 5.1: 75 percent / hydrogen / Pd(OH)2/C / ethyl acetate / 25 h / 25 °C View Scheme
参考文献
Amat, Mercedes; Canto, Margalida; Llor, Nuria; Escolano, Carmen; Molins, Elies; Espinosa, Enrique; Bosch, Joan
Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5343 - 5351
343947-52-4
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1: 49 percent / toluene / 24 h / Heating 2: 72 percent / LiAlH4 / tetrahydrofuran / 1 h / 20 °C 3: 75 percent / hydrogen / Pd(OH)2/C / ethyl acetate / 25 h / 25 °C View Scheme
参考文献
Amat, Mercedes; Canto, Margalida; Llor, Nuria; Escolano, Carmen; Molins, Elies; Espinosa, Enrique; Bosch, Joan
Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5343 - 5351
430461-23-7
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1: 72 percent / LiAlH4 / tetrahydrofuran / 1 h / 20 °C 2: 75 percent / hydrogen / Pd(OH)2/C / ethyl acetate / 25 h / 25 °C View Scheme
参考文献
Amat, Mercedes; Canto, Margalida; Llor, Nuria; Escolano, Carmen; Molins, Elies; Espinosa, Enrique; Bosch, Joan
Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5343 - 5351
911676-21-6
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1.1: SmI2 / methanol; tetrahydrofuran / 5 h / 0 - 20 °C 1.2: 87 percent / NEt3 / CH2Cl2 / 0.5 h / 20 °C 2.1: 76 percent / dimethylformamide / 50 °C 3.1: 85 percent / 2nd generation Grubbs catalyst / CH2Cl2 / 3.5 h / Heating 4.1: 72 percent / H2 / Pd/C / ethanol; ethyl acetate View Scheme
参考文献
Nemoto, Tetsuhiro; Jin, Long; Nakamura, Hiroshi; Hamada, Yasumasa
Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6577 - 6581
911465-34-4
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1: 76 percent / dimethylformamide / 50 °C 2: 85 percent / 2nd generation Grubbs catalyst / CH2Cl2 / 3.5 h / Heating 3: 72 percent / H2 / Pd/C / ethanol; ethyl acetate View Scheme
参考文献
Nemoto, Tetsuhiro; Jin, Long; Nakamura, Hiroshi; Hamada, Yasumasa
Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6577 - 6581
917810-87-8
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1: 85 percent / 2nd generation Grubbs catalyst / CH2Cl2 / 3.5 h / Heating 2: 72 percent / H2 / Pd/C / ethanol; ethyl acetate View Scheme
参考文献
Nemoto, Tetsuhiro; Jin, Long; Nakamura, Hiroshi; Hamada, Yasumasa
Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6577 - 6581
4663-33-6
反式-1,3-二苯基-2-丙烯-1-醇
→
反应条件
430461-56-6
(R)-3-苯基哌啶
反应条件
1.1: pyridine; DMAP / tetrahydrofuran / 20 °C 2.1: 88 percent / aspartic acid-derived P-chirogenic diaminophosphine oxide; BSA; iPr2NEt / (η3-C3H5PdCl)2 / 3.5 h / 20 °C 3.1: SmI2 / methanol; tetrahydrofuran / 5 h / 0 - 20 °C 3.2: 87 percent / NEt3 / CH2Cl2 / 0.5 h / 20 °C 4.1: 76 percent / dimethylformamide / 50 °C 5.1: 85 percent / 2nd generation Grubbs catalyst / CH2Cl2 / 3.5 h / Heating 6.1: 72 percent / H2 / Pd/C / ethanol; ethyl acetate View Scheme
参考文献
Nemoto, Tetsuhiro; Jin, Long; Nakamura, Hiroshi; Hamada, Yasumasa
Tetrahedron Letters, 2006 , vol. 47, # 37 p. 6577 - 6581
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