1,2-二溴-3,3,3-三氟丙烷合成路线 （共 19 条）
参考文献
Stepanova, N. P.; Kuz'mina, N. Ya.; Turbanova, E. S.; Petrov, M. L.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 9 p. 1667 - 1670
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 9 p. 1857 - 1861
参考文献
Haszeldine
Journal of the Chemical Society, 1951 , p. 2495,2503
反应条件
lithium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=100°C; P=7500.75 Torr; 5 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.; SAGAMI CHEMICAL RESEARCH CENTER
Patent: EP1637514 A1, 2006 ;
Location in patent: Page/Page column 17 ;
反应条件
potassium hydroxide; triphenyl-arsane; water; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran; ethylene glycol dimethyl ether T=70°C; Substitution; Suzuki-coupling reaction; 10 h;
参考文献
Pan, Rui-Qi; Liu, Xing-Xin; Deng, Min-Zhi
Journal of Fluorine Chemistry, 1999 , vol. 95, # 1-2 p. 167 - 170
参考文献
Goetzoe, Stephan P.; Seebach, Dieter
Chimia, 1996 , vol. 50, # 1-2 p. 20 - 23
参考文献
Haszeldine
Journal of the Chemical Society, 1951 , p. 2495,2503
反应条件
triethylamine; PdCl2(PPh)2 in N,N-dimethyl-formamide
T=100°C; P=34200 Torr; 1 h;
参考文献
Fuchikami, Takamasa; Ojima, Iwao
Tetrahedron Letters, 1982 , vol. 23, # 40 p. 4099 - 4100
反应条件
triethylamine; PdCl2(PPh)2 in N,N-dimethyl-formamide
T=100°C; P=34200 Torr; 1 h;
参考文献
Fuchikami, Takamasa; Ojima, Iwao
Tetrahedron Letters, 1982 , vol. 23, # 40 p. 4099 - 4100
反应条件
lithium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
T=100°C; P=7500.75 Torr; 5 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.; SAGAMI CHEMICAL RESEARCH CENTER
Patent: EP1637514 A1, 2006 ;
Location in patent: Page/Page column 5; 6 ;
