1: ethyl 3,3,3-trifluoro-2-hydroxypropanoate With sodium tetrahydroborate in ethanol
T=20°C; 12 h;
2: C5H8BF3O3 With sulfuric acid in methanol; water
24 h; Heating / reflux;
参考文献
Central Glass Company, Limited
Patent: US2004/49076 A1, 2004 ;
Location in patent: Page 5; 6 ;
pyridine; Na2S2O5; osmium(VIII) oxide
multistep reaction; stoichiometric and catalytic oxidation of electron-poor olefins with OsO4; other fluoroolefins;
参考文献
Herrmann, Wolfgang A.; Eder, Stefan J.
Chemische Berichte, 1993 , vol. 126, # 1 p. 31 - 38