1,1,2-三氯-3,3,3-三氟丙稀合成路线 (共 179 条)
反应条件
Catalyst M-Chromium oxide T=300°C; ΔHr, ΔSr; Thermodynamic data;
参考文献
Coulson, D. Robert
Journal of Fluorine Chemistry, 1990 , vol. 50, # 1 p. 77 - 87
参考文献
Prober
Journal of the American Chemical Society, 1954 , vol. 76, p. 4189
反应条件
T=155°C; unter Druck;
参考文献
Brown; Whalley
Journal of the Society of Chemical Industry, London, 1948 , vol. 67, p. 331
反应条件
T=100°C; unter Druck;
参考文献
du Pont de Nemours and Co.
Patent: US2404706 , 1943 ;
反应条件
hydrogen fluoride; chlorine; chromium cobalt oxide in nitrogen T=300 - 400°C; P=760.051 Torr; 0.00416667 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2004/18397 A1, 2004 ;
Location in patent: Page 22; 25 ;
反应条件
hydrogen fluoride; chlorine; Cr(NO3)3/Zn(NO3)2 95/5 calcined at 900 C T=280 - 320°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37742 A1, 2005 ;
Location in patent: Page/Page column 15-16; 17 ;
反应条件
hydrogen fluoride; chlorine; copper-substituted α-chromium oxide (98percent chromium/2percent copper) treated with HF T=280°C; P=760.051 Torr; 0.00138889 h; Inert atmosphereMonel.(TM). nickel alloy tube packed with Monel.(TM). turnings; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Rosenfeld, H. David; Sievert, Allen; Subramoney, Shekhar
Patent: US2010/152503 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
hydrogen fluoride; chlorine; copper-substituted α-chromium oxide (95percent chromium/5percent copper) treated with HF T=320°C; P=760.051 Torr; 0.00833333 h; Inert atmosphereMonel.(TM). nickel alloy tube packed with Monel.(TM). turnings; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Rosenfeld, H. David; Sievert, Allen; Subramoney, Shekhar
Patent: US2010/152503 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
hydrogen fluoride; chlorine; cobalt(II) chromite in nitrogen T=375°C; P=760.051 Torr; 0.00416667 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2004/18397 A1, 2004 ;
Location in patent: Page 23; 25 ;
反应条件
hydrogen fluoride; chlorine; Cr(NO3)3/Zn(NO3)2 98/2 calcined at 450 C T=320°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37742 A1, 2005 ;
Location in patent: Page/Page column 15-16; 17 ;