1,1,1,2,3,3-六氟丙烷合成路线 (共 44 条)
反应条件
hydrogen fluoride; 1percent Pd supported on fluorided alumina catalyst T=125 - 300°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37742 A1, 2005 ;
Location in patent: Page/Page column 16; 19 ;
反应条件
SbF5 T=21 - 45°C; 1 - 19 h; Product distribution / selectivity;
参考文献
INEOS FLUOR HOLDINGS LIMITED
Patent: WO2008/125825 A2, 2008 ;
Location in patent: Page/Page column 15-17 ;
反应条件
chromium oxyfluoride (<100 ppm of alkali metals, surface area 40-55 m2/gm) T=348°C; 2 - 29 h; Product distribution / selectivity;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/8350 A2, 2008 ;
Location in patent: Page/Page column 9-11 ;
反应条件
hydrogen; 0.5percent Pd/Al2O3 fluorinated by HF T=200°C; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/79265 A1, 2008 ;
Location in patent: Page/Page column 15-17 ;
反应条件
1,2-dimethylethane T=310°C; 132 h; Further byproducts given;
参考文献
Davies, Terry; Haszeldine, Robert N.; Rowland, Ronald; Tipping, Anthony E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 1 p. 109 - 114
反应条件
bis-maleimidodiphenyl-methane acid T=280°C; 72 h; Further byproducts given. Yields of byproduct given;
参考文献
Haszeldine, Robert N.; Raynor, Clive M.; Tipping, Anthony E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 11 p. 2801 - 2806
反应条件
1,1,1-trifluoropentane T=295°C; 96 h; Further byproducts given;
参考文献
Davies, Terry; Haszeldine, Robert N.; Tipping, Anthony E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 7 p. 1353 - 1356
反应条件
triethylsilane; meta-chloroperoxybenzoic acid 1) 25 deg C, 1 h, 2) 100 deg C, 12 h; Yield givenYields of byproduct given;
参考文献
Petrov, Viacheslav A.
Journal of Organic Chemistry, 1998 , vol. 63, # 21 p. 7294 - 7297
反应条件
T=300°C; 72 h; Further byproducts given;
参考文献
Davies, Terry; Haszeldine, Robert N.; Rowland, Ronald; Tipping, Anthony E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 1 p. 109 - 114
反应条件
T=300°C; 72 h; Further byproducts given;
参考文献
Davies, Terry; Haszeldine, Robert N.; Rowland, Ronald; Tipping, Anthony E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 1 p. 109 - 114