3-碘季戊四醇氟代丙烷-1合成路线 （共 17 条）
→
83168-66-5(2Z,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯+ 83168-67-6(2E,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯+ 83168-65-4(2Z,4Z)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯
反应条件
tetracarbonylnickel(0) in acetonitrile
other F-alkyl iodides and bromides; Mechanism;
参考文献
Krespan, Carl G.; Dixon, David A.
Journal of Organic Chemistry, 1998 , vol. 63, # 1 p. 36 - 43
→
83168-66-5(2Z,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯+ 83168-67-6(2E,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯+ 83168-65-4(2Z,4Z)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯
反应条件
tetracarbonylnickel(0) in acetonitrile
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Krespan, Carl G.; Dixon, David A.
Journal of Organic Chemistry, 1998 , vol. 63, # 1 p. 36 - 43
→
83168-66-5(2Z,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯+ 83168-67-6(2E,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯+ 83168-65-4(2Z,4Z)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯
反应条件
tetracarbonylnickel(0) in acetonitrile
other F-alkyl iodides and bromides; Mechanism;
参考文献
Krespan, Carl G.; Dixon, David A.
Journal of Organic Chemistry, 1998 , vol. 63, # 1 p. 36 - 43
反应条件
bromine
unter Lichtausschluss;
参考文献
Fainberg; Miller
Journal of the American Chemical Society, 1957 , vol. 79, p. 4170,4174
参考文献
Fainberg; Miller
Journal of the American Chemical Society, 1957 , vol. 79, p. 4170,4174
反应条件
hydrogenchloride; cadmium (II) iodide; cadmium
1) a) DMF, 0 deg C, 1h b) 1h, r.t.; Yield given. Multistep reaction;
参考文献
Burton, Donald J.; Tarumi, Yasuo; Heinze, Pamela L.
Journal of Fluorine Chemistry, 1990 , vol. 50, # 2 p. 257 - 263
参考文献
Fainberg; Miller
Journal of the American Chemical Society, 1957 , vol. 79, p. 4170,4174
