Ru aquoxide in not given react. of CS2 and alkylamine with freshly pptd. Ru aquoxide;;

in ethanol T=20°C; 0.333333 h;

in water byproducts: [N(CH3)2CSS]2; RuCl3 was added to aq. soln. Me2NCS2Na (1:3); ppt. was filtered off, washed with water and dried in vacuo over P2O5, prep. column chromy. on silica; elem. anal.;

in not given pptn. of K2(RuCl6) soln. with Na-dialkyldithiocarbamate in coldness;;

in water Ru salt dissolved in H2O; added to aq. soln. of ligand salt (3 equiv.); according to L. Giovagnini et al., Dalton Trans., 2008, 6699; filtered; ppt. washed with H2O; purified by column chromy. (silica gel, CH2Cl2-MeOH 9:1); elem. anal.;