1,3-二(五氟硫基)-5-溴苯合成路线 （共 4 条）
反应条件
N-bromosuccinmide; sulfuric acid
T=60 - 65°C; 22 h; Sealed;
参考文献
IMandamp;T RESEARCH, INC.; UMEMOTO, Teruo
Patent: WO2010/33930 A1, 2010 ;
Location in patent: Page/Page column 35-36 ;
反应条件
1: potassium fluoride; chlorine / acetonitrile / 20 °C / Cooling with ice
2: SbF5 / dichloromethane / 5 h / -85 - -15 °C
View Scheme
参考文献
Umemoto, Teruo; Garrick, Lloyd M.; Saito, Norimichi
Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 461 - 471
反应条件
1: 1-methyl-pyrrolidin-2-one / 20 °C / Cooling with ice
2: AlCl3, aluminium chloride / toluene / 65 h / 20 °C / Inert atmosphere
3: potassium fluoride; chlorine / acetonitrile / 20 °C / Cooling with ice
4: SbF5 / dichloromethane / 5 h / -85 - -15 °C
View Scheme
参考文献
Umemoto, Teruo; Garrick, Lloyd M.; Saito, Norimichi
Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 461 - 471
反应条件
1: 1-methyl-pyrrolidin-2-one / 20 °C / Cooling with ice
2: AlCl3, aluminium chloride / toluene / 65 h / 20 °C / Inert atmosphere
3: potassium fluoride; chlorine / acetonitrile / 20 °C / Cooling with ice
4: SbF5 / dichloromethane / 5 h / -85 - -15 °C
View Scheme
参考文献
Umemoto, Teruo; Garrick, Lloyd M.; Saito, Norimichi
Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 461 - 471
