1,2-双(三氟甲基)苯合成路线 （共 54 条）
反应条件
2,2-dimethyl-1-oxa-2-silacyclohexa-3,5-diene; 1,1,1,4,4,4-hexafluoro-2-butyne T=64°C; 6.5 h; Yield given. Yields of byproduct given;
参考文献
Hussmann, Gregory; Wulff, William D.; Barton, Thomas J.
Journal of the American Chemical Society, 1983 , vol. 105, # 5 p. 1263 - 1269
参考文献
Liu,R.S.H.; Krespan,C.G.
Journal of Organic Chemistry, 1969 , vol. 34, p. 1271 - 1278
反应条件
1,1,1,4,4,4-hexafluoro-2-butyne T=64°C; 6.5 h; Yield given. Yields of byproduct given;
参考文献
Hussmann, Gregory; Wulff, William D.; Barton, Thomas J.
Journal of the American Chemical Society, 1983 , vol. 105, # 5 p. 1263 - 1269
反应条件
copper(l) iodide; silver fluoride; sodium t-butanolate; N-methyl-2-(methylamino)ethylamine in 1-methyl-pyrrolidin-2-one T=20 - 90°C; 5.5 h; Inert atmosphere;
参考文献
Weng, Zhiqiang; Lee, Richmond; Jia, Weiguo; Yuan, Yaofeng; Wang, Wenfeng; Feng, Xue; Huang, Kuo-Wei
Organometallics, 2011 , vol. 30, # 11 p. 3229 - 3232
反应条件
oxygen; triethylamine tris(hydrogen fluoride) in N,N-dimethyl-formamide; toluene T=0°C; 5 h;
参考文献
Novak, Petr; Lishchynskyi, Anton; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 31 p. 7767 - 7770
反应条件
in benzene-d6 T=400°C;
参考文献
Maier, Guenther; Henkelmann, Jochem; Reisenauer, Hans Peter
Angewandte Chemie, 1985 , vol. 97, # 12 p. 1061 - 1063
反应条件
sulfur(IV) fluoride; hydrogen fluoride T=150°C; 20 h;
参考文献
Dmowski, W.
Polish Journal of Chemistry, 1994 , vol. 68, # 11 p. 2175 - 2180
反应条件
in benzene-d6 T=400°C;
参考文献
Maier, Guenther; Henkelmann, Jochem; Reisenauer, Hans Peter
Angewandte Chemie, 1985 , vol. 97, # 12 p. 1061 - 1063
反应条件
sulfur(IV) fluoride; hydrogen fluoride T=160°C; 45 h;
参考文献
Dmowski, W.
Polish Journal of Chemistry, 1994 , vol. 68, # 11 p. 2175 - 2180
反应条件
sulfur(IV) fluoride T=120°C; unter Druck;
参考文献
Du Pont de Nemours and Co.
Patent: US2859245 , 1956 ;
