1-对茴香基-1-苯基乙烯合成路线 （共 99 条）
反应条件
tetrakis(triphenylphosphine) palladium(0); oxygen; copper(l) chloride; lithium tert-butylate in 1,4-dioxane
T=70°C; 7 h;
参考文献
Zhao, Xia; Jing, Jing; Lu, Kui; Zhang, Yan; Wang, Jianbo
Chemical Communications, 2010 , vol. 46, # 10 p. 1724 - 1726
反应条件
1: in tetrahydrofuran
Wittig Olefination; 0.25 h; Inert atmosphere;
2: With potassium tert-butylate in tetrahydrofuran
T=40°C; 1.41667 h; Inert atmosphere;
参考文献
Purohit, Vikram C.; Allwein, Shawn P.; Bakale, Roger P.
Organic Letters, 2013 , vol. 15, # 7 p. 1650 - 1653
反应条件
sodium acetate; tetraphenyl-phosphonium chloride; dipalladium(II); trans-di(μ-acetato)-bislt;o-(di-o-tolylphosphino)benzylgt; in various solvent(s)
T=150°C; 14 h; Yield givenYields of byproduct given. Title compound not separated from byproducts;
参考文献
Herrmann, Wolfgang A.; Boehm, Volker P.W.
Journal of Organometallic Chemistry, 1999 , vol. 572, # 1 p. 141 - 145
反应条件
sodium acetate; [Pd(NH3)4](2+)-loaded NaY in N,N-dimethyl acetamide
T=140°C; Heck olefination; 20 h;
参考文献
Djakovitch, Laurent; Heise, Henrike; Koehler, Klaus
Journal of Organometallic Chemistry, 1999 , vol. 584, # 1 p. 16 - 26
反应条件
2C8H8NO2(1-)*2Cl(1-)*2Pd(2+); tetrabutylammomium bromide; potassium carbonate in water
T=120°C; Suzuki-Miyaura coupling; 14 h; Sealed vessel; stereoselective reaction;
参考文献
Alacid, Emilio; Najera, Carmen
Journal of Organic Chemistry, 2009 , vol. 74, # 6 p. 2321 - 2327
反应条件
1: triethylamine / CH2Cl2
2: LiCl; isoquinoline / PdCl2 / various solvent(s) / 160 °C
View Scheme
参考文献
Goossen, Lukas J.; Paetzold
Angewandte Chemie - International Edition, 2002 , vol. 41, # 7 p. 1237 - 1241
反应条件
(benzyl)-tri-(butyl)-ammonium chloride; bis(benzonitrile)palladium(II) dichloride in o-xylene
Mizoroki-Heck type arylation; 3 h; Heating;
参考文献
Sugihara, Toru; Satoh, Tetsuya; Miura, Masahiro
Tetrahedron Letters, 2005 , vol. 46, # 48 p. 8269 - 8271
反应条件
potassium phosphate; Ni(PCy3)2Cl2; water in 1,4-dioxane; toluene
T=110°C; Suzuki-Miyaura coupling; 20 h; Inert atmosphere;
参考文献
Sun, Chang-Liang; Yang, Wang; Xiao, Zhou; Wu, Zhen-Hua; Li, Bi-Jie; Guan, Bing-Tao; Shi, Zhang-Jie
Chemistry - A European Journal, 2010 , vol. 16, # 20 p. 5844 - 5847
反应条件
bis-triphenylphosphine-palladium(II) chloride; caesium carbonate in N,N-dimethyl acetamide
T=60°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L.N.; Jadhav, Deepak N.; Venkatesh, Varadhachari
European Journal of Organic Chemistry, 2009 , # 25 p. 4300 - 4306
反应条件
1,3,5,7-tetra-azatricyclo[5.1.1.13,5]decane; dnpf; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran
T=80°C; Heck Reaction; 20 h; Inert atmosphere;
参考文献
Zou, Yinjun; Qin, Liena; Ren, Xinfeng; Lu, Yunpeng; Li, Yongxin; Zhou, Jianrong
Chemistry - A European Journal, 2013 , vol. 19, # 10 p. 3504 - 3511
