3-亚苄基-2,4-戊二酮合成路线 （共 46 条）
反应条件
tri-n-butyl-antimony; copper(l) iodide in benzene T=80°C; 6 h;
参考文献
Liao; Huang
Tetrahedron Letters, 1990 , vol. 31, # 41 p. 5897 - 5900
反应条件
copper dichloride in tetrahydrofuran 60 h; Ambient temperature;
参考文献
Attanasi, Orazio; Filippone, Paolino; Mei, Amedeo
Synthetic Communications, 1983 , vol. 13, # 14 p. 1203 - 1208
反应条件
iodine in nitromethane T=80°C; 4 h;
参考文献
Li, Zhongxian; Duan, Zheng; Wang, Huaiqiu; Tian, Rongqiang; Zhu, Qianrui; Wu, Yangjie
Synlett, 2008 , # 16 p. 2535 - 2539
反应条件
3,4,5,6-tetrachloro-1,2-benzoquinone T=100°C; 8 h; Inert atmosphere;
参考文献
Li, Zhiping; Li, Haijun; Guo, Xingwei; Cao, Lin; Yu, Rong; Li, Huanrong; Pan, Shiguang
Organic Letters, 2008 , vol. 10, # 5 p. 803 - 805
反应条件
in dichloromethane-d2 T=-60°C; Title compound not separated from byproducts;
参考文献
Reich,H.J.; Hoeger,C.A.; Willis,W.W.
Journal of the American Chemical Society, 1982 , vol. 104, p. 2936
反应条件
3,4,5,6-tetrachloro-1,2-benzoquinone T=100°C; 8 h; Inert atmosphere;
参考文献
Li, Zhiping; Li, Haijun; Guo, Xingwei; Cao, Lin; Yu, Rong; Li, Huanrong; Pan, Shiguang
Organic Letters, 2008 , vol. 10, # 5 p. 803 - 805
反应条件
copper dichloride in tetrahydrofuran 72 h; Ambient temperature;
参考文献
Attanasi, Orazio; Filippone, Paolino; Mei, Amedeo
Synthetic Communications, 1983 , vol. 13, # 14 p. 1203 - 1208
反应条件
3 A molecular sieve; piperidinium acetate; potassium carbonate; 1,1'-bis-(diphenylphosphino)ferrocene; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium in toluene T=110°C; Knoevenagel reaction; 24 h;
参考文献
Black, Phillip. J.; Cami-Kobeci, Gerta; Edwards, Michael G.; Slatford, Paul A.; Whittlesey, Michael K.; Williams, Jonathan M. J.
Organic and Biomolecular Chemistry, 2006 , vol. 4, # 1 p. 116 - 125
反应条件
phosphorous acid trimethyl ester in dichloromethane-d2 T=-91°C; Title compound not separated from byproducts;
参考文献
Reich, Hans J.; Hoeger, Carl A.; Willis, W. W., Jr.
Tetrahedron, 1985 , vol. 41, # 21 p. 4771 - 4780
反应条件
1: 1.) 50percent NaH-mineral oil / 1.) THF, 0 deg C, 5 min; 2.) THF 2: O3 / CD2Cl2 / -91 °C 3: 93 percent Spectr. / CD2Cl2 / -60 °C View Scheme
参考文献
Reich, Hans J.; Hoeger, Carl A.; Willis, W. W., Jr.
Tetrahedron, 1985 , vol. 41, # 21 p. 4771 - 4780
