2,2,2-三氟苯乙酮合成路线 （共 295 条）
反应条件
1: p-TsOH / toluene / 12 h / Heating 2: 66 percent / LiHMDS / toluene; tetrahydrofuran / -78 deg C, 1 h; -78 deg C to RT, 3 h; RT, 2 h View Scheme
参考文献
Kiselyov, Alexander S.
Tetrahedron Letters, 1999 , vol. 40, # 22 p. 4119 - 4122
反应条件
sodium naphthalenide in tetrahydrofuran T=0 - 5°C; 2 h;
参考文献
Banerji, Avijit; Bandyopadhyay, Debasish; Basak, Bidyut; Sur, Kumar R.; Paul, Jyoti N.; Banerji, Julie; Chatterjee, Asima
Tetrahedron Letters, 2005 , vol. 46, # 41 p. 7033 - 7035
反应条件
tris(pentafluorophenyl)-borane in toluene T=20°C; Inert atmosphere; chemoselective reaction;
参考文献
European Journal of Organic Chemistry, , # 12 p. 1961 - 1966
反应条件
5 platinum on alumina; hydrogen in toluene T=20°C; P=750.075 Torr;
参考文献
Balazsik, Katalin; Szori, Kornel; Szollosi, Gyoergy; Bartok, Mihaly
Catalysis Communications, 2011 , vol. 12, # 15 p. 1410 - 1414
反应条件
sodium hydroxide in water T=25°C; different concentrations of the base; KineticsRate constant;
参考文献
Simons; Ramler
Journal of the American Chemical Society, 1943 , vol. 65, p. 389,390
反应条件
hydroxide reaction enthalpies; Product distributionThermodynamic data;
参考文献
Staneke, Paul O.; Ingemann, Steen; Nibbering, Nico M. M.
Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands, 1996 , vol. 115, # 3 p. 179 - 184
反应条件
in N,N-dimethyl acetamide T=120 - 130°C; 24 h;
参考文献
Hao; Ge; Yang
Synthetic Communications, 2003 , vol. 33, # 1 p. 79 - 86
反应条件
in N,N-dimethyl acetamide T=120 - 130°C; 24 h;
参考文献
Hao; Ge; Yang
Synthetic Communications, 2003 , vol. 33, # 1 p. 79 - 86
反应条件
1.1: 52 percent 2.1: 73 percent / NaH / tetrahydrofuran / 20 °C 3.1: O3 / CH2Cl2 / -78 °C 3.2: 54 percent / Me2S / CH2Cl2 / -78 - 20 °C 4.1: NaClO2; KH2PO4; isobutene / 2-methyl-propan-2-ol; H2O / 16 h / 20 °C View Scheme
参考文献
Bravo, Pierfrancesco; Frigerio, Massimo; Resnati, Guiseppe
Journal of Organic Chemistry, 1990 , vol. 55, # 13 p. 4216 - 4218
反应条件
copper(l) iodide; 1,10-phenanthroline in o-xylene T=150°C; 6 h; Inert atmosphere;
参考文献
Nakatani, Yuji; Koizumi, Yuichiro; Yamasaki, Ryu; Saito, Shinichi
Organic Letters, 2008 , vol. 10, # 10 p. 2067 - 2070
