2,2,2-三氟苯乙酮合成路线 (共 295 条)
反应条件
1: ethyl magnesium chloride With lithium chloride in tetrahydrofuran T=20°C; 1 h; Inert atmosphere; 2: 2,2,2-Trifluoro-1-phenyl-ethanone in tetrahydrofuran T=0 - 20°C; 48 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 17, # 30 p. 8333 - 8341
反应条件
phenyl-magnesium bromide in tetrahydrofuran; diethyl ether T=65°C; Tishchenko reaction; 4 h; Inert atmosphere;
参考文献
Cronin, Linda; Manoni, Francesco; O'Connor, Cornelius J.; Connon, Stephen J.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 17 p. 3045 - 3048
反应条件
in diethyl ether T=20°C; 18 h;
参考文献
Journal of Fluorine Chemistry, , vol. 127, # 1 p. 150 - 152
反应条件
diethylzinc in diethyl ether T=20°C; 5 h; Product distribution; Further Variations:ReagentsSolventsreagent ratio, reaction time;
参考文献
Sasaki, Shigeru; Yamauchi, Takayasu; Kubo, Hajime; Kanai, Masatomi; Ishii, Akihiro; Higashiyama, Kimio
Tetrahedron Letters, 2005 , vol. 46, # 9 p. 1497 - 1500
反应条件
1: With C58H44N2 in hexane; toluene T=-37°C; Inert atmosphere; 2: With water; ammonium chloride in hexane; toluene Kinetics; Reagent/catalyst;
参考文献
Genov, Miroslav; Martinez-Ilarduya, Jesus M.; Calvillo-Barahona, Mercedes; Espinet, Pablo
Organometallics, 2010 , vol. 29, # 23 p. 6402 - 6407
反应条件
Irradiation; Quantum yieldMechanism;
参考文献
Wagner, Peter J.; Truman, Royal J.; Scaiano, J. C.
Journal of the American Chemical Society, 1985 , vol. 107, # 24 p. 7093 - 7097
反应条件
in sulfolane borate buffer pH=8.3; KineticsRate constant;
参考文献
Bossaerts, Jan; Dommisse, Roger A.; Alderweireldt, Frank C.
Tetrahedron Letters, 1984 , vol. 25, # 21 p. 2235 - 2236
反应条件
in sulfolane borate buffer pH=8.3; KineticsRate constant;
参考文献
Bossaerts, Jan; Dommisse, Roger A.; Alderweireldt, Frank C.
Tetrahedron Letters, 1984 , vol. 25, # 21 p. 2235 - 2236
反应条件
in sulfolane borate buffer pH=8.3; KineticsRate constant;
参考文献
Bossaerts, Jan; Dommisse, Roger A.; Alderweireldt, Frank C.
Tetrahedron Letters, 1984 , vol. 25, # 21 p. 2235 - 2236
反应条件
in sulfolane borate buffer pH=8.3; KineticsRate constant;
参考文献
Bossaerts, Jan; Dommisse, Roger A.; Alderweireldt, Frank C.
Tetrahedron Letters, 1984 , vol. 25, # 21 p. 2235 - 2236