2,2,2-三氟苯乙酮合成路线 （共 295 条）
反应条件
[Ru(II)(2,2’-bipyridine)3]Cl2 in methanol 15 h; Irradiation;
参考文献
Journal of Organic Chemistry, , vol. 48, # 17 p. 2941 - 2942
反应条件
phenyl-magnesium bromide in tetrahydrofuran; diethyl ether T=65°C; Tishchenko reaction; 24 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 17 p. 3045 - 3048
反应条件
in diethyl ether 4 h; ultrasound, 2 molar equiv. allylmagnesium bromide;
参考文献
Felix, Caroline; Laurent, Andre; Mison, Pierre
Tetrahedron Letters, 1990 , vol. 31, # 29 p. 4143 - 4144
反应条件
iso-PrOLi in toluene T=20 - 80°C; 6 h;
参考文献
Journal of Fluorine Chemistry, , vol. 127, # 1 p. 150 - 152
反应条件
sodium hydroxide in tetrahydrofuran; water T=0 - 20°C; Cannizzaro-type reaction;
参考文献
Jiang, Xin-Dong; Matsukawa, Shiro; Kakuda, Ken-Ichiro; Fukuzaki, Yuta; Zhao, Wei-Li; Li, Lin-Song; Shen, Huai-Bin; Kojima, Satoshi; Yamamoto, Yohsuke
Dalton Transactions, 2010 , vol. 39, # 41 p. 9823 - 9829
反应条件
NaHCO3 - Na2CO3 buffer in water; isopropyl alcohol T=50°C; deuterium isotope effect; MechanismRate constant;
参考文献
Chipman, David M.; Yaniv, Ruth; Eikeren, Paul van
Journal of the American Chemical Society, 1980 , vol. 102, # 9 p. 3244 - 3246
反应条件
NaHCO3 - Na2CO3 buffer in water; isopropyl alcohol T=50°C; deuterium isotope effect; MechanismRate constant;
参考文献
Chipman, David M.; Yaniv, Ruth; Eikeren, Paul van
Journal of the American Chemical Society, 1980 , vol. 102, # 9 p. 3244 - 3246
反应条件
sodium hydroxide in N,N-dimethyl-formamide T=20°C; Cannizzaro-type reaction; 10 h; Inert atmosphere;
参考文献
Jiang, Xin-Dong; Matsukawa, Shiro; Kakuda, Ken-Ichiro; Fukuzaki, Yuta; Zhao, Wei-Li; Li, Lin-Song; Shen, Huai-Bin; Kojima, Satoshi; Yamamoto, Yohsuke
Dalton Transactions, 2010 , vol. 39, # 41 p. 9823 - 9829
反应条件
1: ethyl magnesium chloride With lithium chloride in tetrahydrofuran T=20°C; 1 h; Inert atmosphere; 2: 2,2,2-Trifluoro-1-phenyl-ethanone in tetrahydrofuran T=0 - 20°C; 48 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 17, # 30 p. 8333 - 8341
反应条件
phenyl-magnesium bromide in tetrahydrofuran; diethyl ether T=65°C; Tishchenko reaction; 4 h; Inert atmosphere;
参考文献
Cronin, Linda; Manoni, Francesco; O'Connor, Cornelius J.; Connon, Stephen J.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 17 p. 3045 - 3048
