2,2,2-三氟苯乙酮合成路线 （共 295 条）
反应条件
hydrogen in toluene T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Balazsik, Katalin; Szori, Kornel; Szollosi, Gyoergy; Bartok, Mihaly
Catalysis Communications, 2011 , vol. 12, # 15 p. 1410 - 1414
反应条件
1: 90 percent 2: hydrolysis View Scheme
参考文献
Hull, William E.; Seeholzer, Klaus; Baumeister, Marlies; Ugi, Ivar
Tetrahedron, 1986 , vol. 42, # 2 p. 547 - 552
反应条件
triphenylphosphine; benzoic acid; methyltrioxorhenium (VII) in toluene T=80°C; 48 h;
参考文献
Pedro, Filipe M.; Hirner, Sebastian; Kuehn, Fritz E.
Tetrahedron Letters, 2005 , vol. 46, # 45 p. 7777 - 7779
参考文献
Huff, Roger K.; Savins, Eric G.
Journal of the Chemical Society, Chemical Communications, 1980 , # 15 p. 742 - 743
反应条件
n-butyllithium 1.) Et2O, hexane, RT, 30 min, 2.) Et2O, RT, 17 h; Yield given. Multistep reaction;
参考文献
Ohno, Nobuhiro; Fukamiya, Narihiko; Okano, Masayoshi; Tagahara, Kiyoshi; Lee, Kuo-Hsiung
Bioorganic and Medicinal Chemistry, 1997 , vol. 5, # 8 p. 1489 - 1495
反应条件
1: 65 percent / BuLi / tetrahydrofuran / 0 - 25 °C 2: aq. K3Fe(CN)6, K2CO3, (DHQD)2-DPP, OsO4 / 2-methyl-propan-2-ol; toluene / 72 h / 0 °C View Scheme
参考文献
Bennani; Vanhessche; Sharpless
Tetrahedron Asymmetry, 1994 , vol. 5, # 8 p. 1473 - 1476
反应条件
baker's yeast in water T=32°C; 4 h;
参考文献
Bucciarelli, Maria; Forni. Arrigo; Moretti, Irene; Torre, Giovanni
Synthesis, 1983 , # 11 p. 897 - 899
反应条件
anhydrous magnesium perchlorate; chiral bis(1,4-dihydronicotinamide) in chloroform; acetonitrile T=50°C; 11 h; influence of the chiral reagent; Product distribution;
参考文献
Bradshaw, Curt W.; Fu, Hong; Shen, Gwo-Jenn; Wong, Chi-Huey
Journal of Organic Chemistry, 1992 , vol. 57, # 5 p. 1526 - 1532
反应条件
hydrogen in toluene T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Balazsik, Katalin; Szori, Kornel; Szollosi, Gyoergy; Bartok, Mihaly
Catalysis Communications, 2011 , vol. 12, # 15 p. 1410 - 1414
反应条件
hydrogen in toluene T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Balazsik, Katalin; Szori, Kornel; Szollosi, Gyoergy; Bartok, Mihaly
Catalysis Communications, 2011 , vol. 12, # 15 p. 1410 - 1414
