1,2-二氯四甲基二硅烷合成路线 （共 115 条）
反应条件
aluminium trichloride; acetyl chloride T=125°C; Title compound not separated from byproducts;
参考文献
Knopf; Herzog; Roewer; Brendler; Rheinwald; Lang
Journal of Organometallic Chemistry, 2002 , vol. 662, # 1-2 p. 14 - 22
反应条件
(i) Mg, THF, (ii) /BRN= 1736173/; Multistep reaction;
参考文献
Kumada,M. et al.
Journal of Organometallic Chemistry, 1964 , vol. 2, p. 136 - 145
反应条件
triethylamine in dichloromethane T=0°C; 1 h;
参考文献
Denmark, Scott E.; Kallemeyn, Jeffrey M.
Organic Letters, 2003 , vol. 5, # 19 p. 3483 - 3486
参考文献
General Electric Company
Patent: US4709054 A1, 1987 ;
反应条件
2-methyl-1H-imidazole; tetra-n-butyl phosphonium chloride T=172 - 177°C; P=5155.93 Torr; 1 h; Autoclave;
参考文献
MOMENTIVE PERFORMANCE MATERIALS INC.; LEWIS, Kenrick, M.; NEELY, John, D.
Patent: WO2013/101619 A1, 2013 ;
Location in patent: Paragraph 0092; 0095 ;
反应条件
2-methyl-1H-imidazole; tetra-n-butyl phosphonium chloride T=265°C; P=13689.1 Torr; 3 h; Autoclave;
参考文献
MOMENTIVE PERFORMANCE MATERIALS INC.; LEWIS, Kenrick, M.; NEELY, John, D.
Patent: WO2013/101619 A1, 2013 ;
Location in patent: Paragraph 0098; 0100 ;
反应条件
Cyphos® IL 101; MeImHCl T=80 - 175°C; Inert atmosphere;
参考文献
MOMENTIVE PERFORMANCE MATERIALS INC.; LEWIS, Kenrick, M.; NEELY, John, D.
Patent: WO2013/101619 A1, 2013 ;
Location in patent: Paragraph 00149 ;
参考文献
General Electric Company
Patent: US4918197 A1, 1990 ;
反应条件
hydrogenchloride T=430 - 750°C; 72 h; Conversion of starting material;
参考文献
US2005/113591 A1, ;
Page/Page column 2 ;
反应条件
1-methyl-1H-imidazole in toluene 3 h; Heating; Product distribution;
参考文献
Journal of Organometallic Chemistry, , vol. 507, # 1-2 p. 221 - 228
