(3,3-二甲氧基-1-丙炔基)环丙烷合成路线 (共 2 条)
反应条件
1: ethyl bromide With magnesium in tetrahydrofuran T=50 - 60°C; Heating / reflux; 2: cyclopropyl acetylene in tetrahydrofuran; toluene T=20°C; 1.5 h; 3: With trimethyl orthoformate in tetrahydrofuran; toluene T=100 - 120°C; 4 h;
参考文献
WO2005/14586 A1, ;
Page/Page column 10; 11 ;
反应条件
2-{2-(2-hydroxyethyl)thioethyl}thioethanol; hydrogen; Lindlar's catalyst in ethyl acetate
P=750.075 Torr; 2.5 h;
参考文献
ARPIDA AG
Patent: WO2005/14586 A1, 2005 ;
Location in patent: Page/Page column 11 ;