C2D4 in solid matrix
byproducts: CD2CD2S; Irradiation (UV/VIS); photolysis of solid matrix Ar:C2D4:OCS=100:1:1 using unfiltered emission from Hg or Cd-arc for 320 min at 20 K; mechanism discussed;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334
acetylene in solid matrix
byproducts: H2CCS, HCCSH, HCCHS; Irradiation (UV/VIS); photolysis of solid matrix Ar:C2H2:OCS=100:1:1 using unfiltered emission from Cd-arc for 240 min at 20 K; mechanism discussed;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334
in benzene
Irradiation (UV/VIS); photolytic decomposition of cyclic compounds with dioxy-ethylene-bridge;; not isolated, detected by mass spectroscopy;;
参考文献
Strating et al.
Tetrahedron Letters, 1969 , p. 125
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Gmelin Handbook: C: MVol.C1, 46, page 99 - 102
in solid matrix
byproducts: S[PF3](n); Irradiation (UV/VIS); photolysis of solid matrix Ar:OCS:PF3=100:1:1 using unfiltered emissionof Hg arc for 55 min at 20 K; with or without annealing matrix to 38 K for 10 min;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334
in solid matrix
Irradiation (UV/VIS); photolysis of solid matrix Ar:OCS:PCl3=100:1:1 using unfiltered emission of Hg arc 20 K for 60 min;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334