1: lithium phenylacetylide With indium(III) chloride in tetrahydrofuran; hexane
T=-78 - 20°C;
2: carbon monoxide; 1-(iodo)-4-methylbenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; hexane
T=60°C; 1.5 h;
参考文献
Lee, Sung Wook; Lee, Kooyeon; Seomoon, Dong; Kim, Sundae; Kim, Hyunseok; Kim, Hyun; Shim, Eunkyong; Lee, Miae; Lee, Seokju; Kim, Misook; Lee, Phil Ho
Journal of Organic Chemistry, 2004 , vol. 69, # 14 p. 4852 - 4855
TMG in tetrahydrofuran; hexane
2 h; Ambient temperaturewithout cat.;
参考文献
Fukuda, Yukitoshi; Matsubara, Seijiro; Lambert, Claude; Shiragami, Hiroshi; Nanko, Toshiki; et al.
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 6 p. 1810 - 1813
in tetrahydrofuran; hexane
1.) -85 deg C to room temperature, 2 h, 2.) room temperature, 22 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
