7H-苯并环庚烯-7-酮合成路线 （共 26 条）
反应条件
1: With N-bromosuccinmide; trimethylsilyl trifluoromethanesulfonate in acetonitrile
T=20°C; 4.5 h;
2: With 1,8-diazabicyclo[5.4.0]undec-7-ene in acetonitrile
T=20°C; 0.5 h;
参考文献
Albrecht, Sebastien; Al-Lakkis-Wehbe, Mira; Orsini, Alban; Defoin, Albert; Pale, Patrick; Salomon, Emmanuel; Tarnus, Celine; Weibel, Jean-Marc
Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 4 p. 1434 - 1449
反应条件
chromium(VI) oxide in pyridine; dichloromethane
T=20°C; 46 h;
参考文献
Dastan; Yildiz; Balci
Synthetic Communications, 2001 , vol. 31, # 24 p. 3807 - 3815
反应条件
chromium(VI) oxide in acetic acid
T=10 - 20°C;
参考文献
Dastan; Yildiz; Balci
Synthetic Communications, 2001 , vol. 31, # 24 p. 3807 - 3815
反应条件
1: 68 percent / NBS; benzoyl peroxide / CCl4 / 2 h / Irradiation; heating
2: 12 percent / SeO2; KH2PO4 / dioxane; H2O / 16 h / Heating
View Scheme
参考文献
Bonvallet, Paul A.; Todd, Eric M.; Kim, Yong Seol; McMahon, Robert J.
Journal of Organic Chemistry, 2002 , vol. 67, # 25 p. 9031 - 9042
反应条件
triethylamine in dichloromethane
0.25 h; Ambient temperature;
参考文献
Regitz, Manfred; Boehshar, Manfred; Arenz, Stefan; Heydt, Heinrich
Chemische Berichte, 1989 , vol. 122, p. 565 - 576
反应条件
potassium dihydrogenphosphate; selenium(IV) oxide in 1,4-dioxane; water
16 h; Heating;
参考文献
Bonvallet, Paul A.; Todd, Eric M.; Kim, Yong Seol; McMahon, Robert J.
Journal of Organic Chemistry, 2002 , vol. 67, # 25 p. 9031 - 9042
反应条件
triethylamine in dichloromethane
0.25 h; Ambient temperature;
参考文献
Regitz, Manfred; Boehshar, Manfred; Arenz, Stefan; Heydt, Heinrich
Chemische Berichte, 1989 , vol. 122, p. 565 - 576
反应条件
1: 16.79 g / p-TsOH*H2O / benzene / 4 h / Heating
2: 68 percent / NBS; benzoyl peroxide / CCl4 / 2 h / Irradiation; heating
3: 12 percent / SeO2; KH2PO4 / dioxane; H2O / 16 h / Heating
View Scheme
参考文献
Bonvallet, Paul A.; Todd, Eric M.; Kim, Yong Seol; McMahon, Robert J.
Journal of Organic Chemistry, 2002 , vol. 67, # 25 p. 9031 - 9042
反应条件
1: NaBH4 / methanol; H2O / 16 h
2: 16.79 g / p-TsOH*H2O / benzene / 4 h / Heating
3: 68 percent / NBS; benzoyl peroxide / CCl4 / 2 h / Irradiation; heating
4: 12 percent / SeO2; KH2PO4 / dioxane; H2O / 16 h / Heating
View Scheme
参考文献
Bonvallet, Paul A.; Todd, Eric M.; Kim, Yong Seol; McMahon, Robert J.
Journal of Organic Chemistry, 2002 , vol. 67, # 25 p. 9031 - 9042
反应条件
1: 88 percent / 0.5 h / Ambient temperature
2: NEt3 / CH2Cl2 / 0.25 h / Ambient temperature
View Scheme
参考文献
Regitz, Manfred; Boehshar, Manfred; Arenz, Stefan; Heydt, Heinrich
Chemische Berichte, 1989 , vol. 122, p. 565 - 576
