二苯并[c,e]氧杂卓-5(7H)-酮合成路线 （共 16 条）
反应条件
1.1: n-BuLi / tetrahydrofuran / 0.17 h / 0 °C
1.2: 78 percent / tetrahydrofuran / 20 °C
2.1: 76 percent / Oxone; OsO4 / dimethylformamide / 0.75 h / 20 °C
View Scheme
参考文献
Schomaker, Jennifer M.; Travis, Benjamin R.; Borhan, Babak
Organic Letters, 2003 , vol. 5, # 17 p. 3089 - 3092
反应条件
1.1: 89 percent / 4-methylmorpholine N-oxide; tetrapropylammonium perruthenate / CH2Cl2 / 1 h / 20 °C
2.1: n-BuLi / tetrahydrofuran / 0.17 h / 0 °C
2.2: 78 percent / tetrahydrofuran / 20 °C
3.1: 76 percent / Oxone; OsO4 / dimethylformamide / 0.75 h / 20 °C
View Scheme
参考文献
Schomaker, Jennifer M.; Travis, Benjamin R.; Borhan, Babak
Organic Letters, 2003 , vol. 5, # 17 p. 3089 - 3092
反应条件
1: 89 percent / diborane / tetrahydrofuran / 2 h / Ambient temperature
2: 86 percent / 150 °C / 0.1 Torr
View Scheme
参考文献
Schloegl, Karl; Schoelm, Richard
Monatshefte fuer Chemie, 1980 , vol. 111, p. 259 - 274
反应条件
1: 89 percent / Ac2O / 1 h / Heating
2: 87 percent / NaBH4 / dimethylformamide / 1 h / Ambient temperature
View Scheme
参考文献
Roehrkasten, Ralf; Kreher, Richard P.
Chemische Berichte, 1991 , vol. 124, # 9 p. 2085 - 2090
参考文献
Kenner; Turner
Journal of the Chemical Society, 1911 , vol. 99, p. 2112
反应条件
RhH(CO)(triphenylphosphine)3
360 h; Heating;
参考文献
Grigg, Ronald; Mitchell, Thomas R. B.; Sutthivaiyakit, Somyote
Tetrahedron, 1981 , vol. 37, # 24 p. 4313 - 4319
