1: H2SO4 / 48 h / Ambient temperature 2: PBr3 / diethyl ether / 1 h / Ambient temperature View Scheme

暂无反应条件数据

sulfuric acid 48 h; Ambient temperature; Yield given;

sulfuric acid in methanol 4 h; Inert atmosphereReflux;

1: sulfuric acid / methanol / 4 h / |Inert atmosphere; |Reflux 2: C29H41IrN3O(2+)*C32H12BF24(1-); hydrogen / dichloromethane / 24 h / 25 °C / 37503.8 Torr View Scheme

1: sulfuric acid / 4 h / |Reflux; |Inert atmosphere 2: (1S,2R,4S,5R)-2-((1S)-(dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yloxy)(6-methoxyquinolin-4-yl)methyl)-5-vinylquinuclidine; [Ir(cycloocta-1,5-diene)2]tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen / dichloromethane / 12 h / 25 °C / 37503.8 Torr View Scheme

1: H2SO4 / 48 h / Ambient temperature 2: PBr3 / diethyl ether / 1 h / Ambient temperature 3: dimethylformamide / 24 h / Ambient temperature 4: 91 percent / DIBAH / tetrahydrofuran; hexane / 0.17 h / -20 °C 5: 56 percent / BuLi / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 0.17 h / -78 °C 6: 45 percent / Na, dibenzo<18>crown-6 / liquid ammonia; tetrahydrofuran / 0.03 h / -78 °C View Scheme