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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
1,2,2-三氟苯乙烯
合成路线
（共 58 条）
116-14-3
四氟乙烯
+
100-59-4
苯基氯化镁
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
反应条件
tris-(dibenzylideneacetone)dipalladium(0); zinc(II) chloride; lithium iodide in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) T=55°C; P=2660.18 Torr; 8 h; Inert atmosphereAutoclave;
参考文献
Ohashi, Masato; Kambara, Tadashi; Hatanaka, Tsubasa; Saijo, Hiroki; Doi, Ryohei; Ogoshi, Sensuke
Journal of the American Chemical Society, 2011 , vol. 133, # 10 p. 3256 - 3259
591-50-4
碘苯
+
811-97-2
1,1,1,2-四氟乙烷
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
反应条件
1: 1,1,1-trifluoro-2-fluoroethane With zinc(II) chloride; lithium diisopropyl amide in tetrahydrofuran T=15 - 20°C; 2: iodobenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=65°C; 3 h;
参考文献
Raghavanpillai, Anilkumar; Burton, Donald J.
Journal of Organic Chemistry, 2004 , vol. 69, # 21 p. 7083 - 7091
116-14-3
四氟乙烯
+
100-59-4
苯基氯化镁
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
+
643-76-5
1 2-二氟二苯乙烯
反应条件
lithium chloride in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) T=20°C; P=2660.18 Torr; 27 h; Inert atmosphere;
参考文献
Ohashi, Masato; Kamura, Ryohei; Doi, Ryohei; Ogoshi, Sensuke
Chemistry Letters, 2013 , vol. 42, # 8 p. 933 - 935
116-14-3
四氟乙烯
+
100-58-3
溴化苯基镁
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
反应条件
tris-(dibenzylideneacetone)dipalladium(0); zinc(II) chloride; lithium iodide in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) T=40°C; P=2660.18 Torr; 8 h; Inert atmosphereAutoclave;
参考文献
Ohashi, Masato; Kambara, Tadashi; Hatanaka, Tsubasa; Saijo, Hiroki; Doi, Ryohei; Ogoshi, Sensuke
Journal of the American Chemical Society, 2011 , vol. 133, # 10 p. 3256 - 3259
116-14-3
四氟乙烯
+
24388-23-6
苯硼酸频哪醇酯
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
反应条件
caesium carbonate; bis(dibenzylideneacetone)-palladium(0); tri-cyclo-hexyl-phosphine in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) T=100°C; P=2660.18 Torr; 5 h;
参考文献
Ohashi, Masato; Saijo, Hiroki; Shibata, Mitsutoshi; Ogoshi, Sensuke
European Journal of Organic Chemistry, 2013 , # 3 p. 443 - 447
116-14-3
四氟乙烯
+
98-80-6
苯硼酸
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
反应条件
tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; tri-cyclo-hexyl-phosphine in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) T=100°C; 2 h; Inert atmosphere; Reagent/catalystTimeSolvent;
参考文献
Daikin Industries; Osaka University; Nagai, Takabumi; Adachi, Kenji; Shibanuma, Takashi; Ogoshi, Sensuke; Ohashi, Masato
Patent: US2013/324757 A1, 2013 ;
Location in patent: Paragraph 0309 ;
116-14-3
四氟乙烯
+
100-58-3
溴化苯基镁
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
+
569-72-2
1-(2,2-二氟-1-苯基乙烯基)-4-氟苯
反应条件
lithium iodide; tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine in tetrahydrofuran; diethyl ether; benzene-d6 T=60°C; P=2625.26 Torr; 2 h; Product distribution / selectivity;
参考文献
Nagai, Takabumi; Shibanuma, Takashi; Ogoshi, Sensuke; Ohashi, Masato
Patent: US2012/330072 A1, 2012 ;
Location in patent: Page/Page column 7 ;
116-14-3
四氟乙烯
+
5123-13-7
5,5-二甲基-2-苯基-1,3,2-二氧硼杂
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
+
569-72-2
1-(2,2-二氟-1-苯基乙烯基)-4-氟苯
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium tert-butylate; tri-cyclo-hexyl-phosphine in tetrahydrofuran; benzene-d6 T=100°C; 16 h; Inert atmosphere;
参考文献
Daikin Industries; Osaka University; Nagai, Takabumi; Adachi, Kenji; Shibanuma, Takashi; Ogoshi, Sensuke; Ohashi, Masato
Patent: US2013/324757 A1, 2013 ;
Location in patent: Paragraph 0287 ;
56424-23-8
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
反应条件
lithium hexamethyldisilazane in tetrahydrofuran T=15°C; 3 h;
参考文献
Anilkumar; Burton, Donald J.
Journal of Fluorine Chemistry, 2005 , vol. 126, # 8 p. 1174 - 1184
116-14-3
四氟乙烯
+
5123-13-7
5,5-二甲基-2-苯基-1,3,2-二氧硼杂
→
反应条件
447-14-3
1,2,2-三氟苯乙烯
+
20488-54-4
(E)-A,A’-二氟芪
+
569-72-2
1-(2,2-二氟-1-苯基乙烯基)-4-氟苯
+
20488-55-5
反应条件
bis(1,5-cyclooctadiene)nickel (0); caesium carbonate; tri-cyclo-hexyl-phosphine in tetrahydrofuran; benzene-d6 T=100°C; 16 h; Inert atmosphere;
参考文献
Daikin Industries; Osaka University; Nagai, Takabumi; Adachi, Kenji; Shibanuma, Takashi; Ogoshi, Sensuke; Ohashi, Masato
Patent: US2013/324757 A1, 2013 ;
Location in patent: Paragraph 0277-0284 ;
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