2,2'-联吡啶-6,6'-二羧酸合成路线 （共 10 条）
反应条件
chromium(VI) oxide; sulfuric acid
T=35°C; Cooling with ice;
参考文献
Bozoklu, Guelay; Marchal, Claire; Gateau, Christelle; Pecaut, Jacques; Imbert, Daniel; Mazzanti, Marinella
Chemistry - A European Journal, 2010 , vol. 16, # 21 p. 6159 - 6163
反应条件
sulfuric acid; acetic acid
T=20°C;
参考文献
Andreiadis, Eugen S.; Demadrille, Renaud; Imbert, Daniel; Pecaut, Jacques; Mazzanti, Marinella
Chemistry - A European Journal, 2009 , vol. 15, # 37 p. 9458 - 9476
反应条件
1: 6,6'-dibromo-2,2'-dipyridyl With n-butyllithium in tetrahydrofuran
Metallation;
2: carbon dioxide Carbonylation; acetylation;
参考文献
Qian, Changtao; Wang, Longcheng
Tetrahedron Letters, 2000 , vol. 41, # 13 p. 2203 - 2206
反应条件
1.1: BuLi / diethyl ether / 2 h / -78 °C
1.2: 40 percent / CuCl2; O2
2.1: 25 percent / BuLi / tetrahydrofuran
View Scheme
参考文献
Qian, Changtao; Wang, Longcheng
Tetrahedron Letters, 2000 , vol. 41, # 13 p. 2203 - 2206
反应条件
1: FeCl3
2: SeO2; pyridine
View Scheme
参考文献
Burstall
Journal of the Chemical Society, 1938 , p. 1662,1669
反应条件
1: copper-powder; biphenyl
2: bromine / 500 °C
3: biphenyl
4: HCl; water
View Scheme
参考文献
Burstall
Journal of the Chemical Society, 1938 , p. 1662,1669
反应条件
1: bromine / 500 °C
2: biphenyl
3: HCl; water
View Scheme
参考文献
Burstall
Journal of the Chemical Society, 1938 , p. 1662,1669
反应条件
1: biphenyl
2: HCl; water
View Scheme
参考文献
Burstall
Journal of the Chemical Society, 1938 , p. 1662,1669
反应条件
sulfuric acid
T=20°C; RefluxInert atmosphere;
参考文献
Bozoklu, Guelay; Marchal, Claire; Gateau, Christelle; Pecaut, Jacques; Imbert, Daniel; Mazzanti, Marinella
Chemistry - A European Journal, 2010 , vol. 16, # 21 p. 6159 - 6163
反应条件
dicyclohexyl-carbodiimide
T=0°C; 3 h;
参考文献
Guillo, Pascal; Hamelin, Olivier; Pecaut, Jacques; Menage, Stephane
Tetrahedron Letters, 2013 , vol. 54, # 8 p. 840 - 842
