1-氧杂螺[5.5]十一烷-2-酮合成路线 （共 23 条）
反应条件
hydrogen; platinum(IV) oxide; ruthenium in dichloromethane
T=20°C; P=760.051 Torr;
参考文献
Cossy, Janine; Bargiggia, Frederic; BouzBouz, Samir
Organic Letters, 2003 , vol. 5, # 4 p. 459 - 462
反应条件
hydrogen; [RhCl(η2:η2-cycloocta-1,5-diene)]2 in 1,4-dioxane
T=110°C; P=37503 Torr; 20 h;
参考文献
Kitsos-Rzychon, Beate; Eilbracht, Peter
Tetrahedron, 1998 , vol. 54, # 36 p. 10721 - 10732
反应条件
jones reagent in acetone
T=0°C; 1 h;
参考文献
Canonne, Persephone; Foscolos, Georges B.; Belanger, Denis
Journal of Organic Chemistry, 1980 , vol. 45, # 10 p. 1828 - 1835
反应条件
jones reagent in acetone
T=0°C; 0.5 h;
参考文献
Georgiadis; Tsekouras; Kotretsou; Haroutounian; Polissiou
Synthesis, 1991 , # 11 p. 929 - 932
反应条件
1: 1,5-dibromo-pentane With magnesium in tetrahydrofuran
1 h; Inert atmosphere;
2: glutaric acid anhydride in tetrahydrofuran
参考文献
Parmar, Dixit; Duffy, Lorna A.; Sadasivam, Dhandapani V.; Matsubara, Hiroshi; Bradley, Paul A.; Flowers II, Robert A.; Procter, David J.
Journal of the American Chemical Society, 2009 , vol. 131, # 42 p. 15467 - 15473
反应条件
pyridine; xanthone powder; bis(2,4-acetylacetonate)cobalt(II); hydrogen in tetrahydrofuran
P=760 Torr; Ambient temperatureIrradiation;
参考文献
Chow, Yuan L.; Huang, Yu-Jin; Dragojlovic, Veljko
Canadian Journal of Chemistry, 1995 , vol. 73, # 5 p. 740 - 742
反应条件
pyridine; xanthone powder; bis(2,4-acetylacetonate)cobalt(II); hydrogen in tetrahydrofuran
P=760 Torr; Ambient temperatureIrradiation;
参考文献
Chow, Yuan L.; Huang, Yu-Jin; Dragojlovic, Veljko
Canadian Journal of Chemistry, 1995 , vol. 73, # 5 p. 740 - 742
反应条件
trifluoroacetic acid in dichloromethane
1 h; Ambient temperature;
参考文献
Yamaguchi, Masahiko; Shibato, Keisuke; Hirao, Ichiro
Tetrahedron Letters, 1984 , vol. 25, # 11 p. 1159 - 1162
反应条件
1: 79 percent / 3-chloroperbenzoic acid / CH2Cl2 / 3 h / Ambient temperature
2: 90 percent / Ag2O / acetone / 24 h / Ambient temperature
3: 95 percent / hydrogen / Pd-C / ethanol / 0.5 h / 825.07 Torr / Ambient temperature
4: 1.) 85 percent aq. hydrazine, 2.) KOH / 1.) ethylene glycol, 100 deg C, 3 h, 2.) 100 deg C, 24 h
5: 94 percent / Jones reagent / acetone / 0.5 h / 0 °C
View Scheme
参考文献
Georgiadis; Tsekouras; Kotretsou; Haroutounian; Polissiou
Synthesis, 1991 , # 11 p. 929 - 932
反应条件
1: 90 percent / Ag2O / acetone / 24 h / Ambient temperature
2: 95 percent / hydrogen / Pd-C / ethanol / 0.5 h / 825.07 Torr / Ambient temperature
3: 1.) 85 percent aq. hydrazine, 2.) KOH / 1.) ethylene glycol, 100 deg C, 3 h, 2.) 100 deg C, 24 h
4: 94 percent / Jones reagent / acetone / 0.5 h / 0 °C
View Scheme
参考文献
Georgiadis; Tsekouras; Kotretsou; Haroutounian; Polissiou
Synthesis, 1991 , # 11 p. 929 - 932
