3-甲基-1-苯基-2-丁烯合成路线 （共 98 条）
反应条件
1: diethyl ether / 0 °C
2: p-toluenesulfonic acid / toluene / 5 h / Heating
View Scheme
参考文献
Von Doering; Benkhoff, Johannes; Carleton, Peter Smart; Pagnotta, Marco
Journal of the American Chemical Society, 1997 , vol. 119, # 45 p. 10947 - 10955
反应条件
in diethyl ether; pentane
T=20°C; 0.25 h;
参考文献
Julia, Marc; Nel, Maurice; Uguen, Daniel
Bulletin de la Societe Chimique de France, 1987 , # 3 p. 487 - 492
反应条件
in tetrahydrofuran
24 h;
参考文献
Matsushita,H.; Negishi,E.I.
Journal of the American Chemical Society, 1981 , vol. 103, p. 2882
反应条件
tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenylphosphine in benzene
T=60°C;
参考文献
Matsuhashi, Hayao; Asai, Satoshi; Hirabayashi, Kazunori; Hatanaka, Yasuo; Mori, Atsunori; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 8 p. 1943 - 1952
反应条件
pyridine; lead(IV) acetate
T=75°C;
参考文献
Strunz, George M.; Ya, Li
Canadian Journal of Chemistry, 1992 , vol. 70, # 5 p. 1317 - 1322
反应条件
copper(l) iodide in diethyl ether
T=-15°C; Inert atmosphere;
参考文献
Tomashevskii; Sokolov; Potekhin
Russian Journal of Organic Chemistry, 2010 , vol. 46, # 12 p. 1822 - 1825
反应条件
palladium diacetate in 1,4-dioxane
T=100°C; Suzuki-Miyaura coupling; 12 h;
参考文献
Gerbino, Dario C.; Mandolesi, Sandra D.; Schmalz, Hans-Guenther; Podesta, Julio C.
European Journal of Organic Chemistry, 2009 , # 23 p. 3964 - 3972
反应条件
1-chloro-2-methyl-N,N-tetramethylenepropenylamine in tetrahydrofuran; dichloromethane
T=-30 - 0°C; 0.75 h;
参考文献
Fujisawa, Tamotsu; Iida, Sachio; Yukizaki, Hisashi; Sato, Toshio
Tetrahedron Letters, 1983 , vol. 24, # 51 p. 5745 - 5748
反应条件
N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran; diethyl ether
T=-78°C; 6 h;
参考文献
Nelson, Donna J.; Nagarajan, Ananthanarayanan
Journal of Organometallic Chemistry, 1993 , vol. 463, # 1-2 p. 1 - 6
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane
T=19°C; 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Babin, D.; Fourneron, J. D.; Harwood, L. M.; Julia, M.
Tetrahedron, 1981 , vol. 37, p. 325 - 332
