3-甲基-1-苯基-2-丁烯合成路线 （共 98 条）
反应条件
1: CH2Cl2; pyridine / Ambient temperature
2: 33 percent / Pd2(dba)3*CHCl3, PPh3 / benzene / 60 °C
View Scheme
参考文献
Matsuhashi, Hayao; Asai, Satoshi; Hirabayashi, Kazunori; Hatanaka, Yasuo; Mori, Atsunori; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 8 p. 1943 - 1952
反应条件
infusorial earht
T=300 - 400°C;
参考文献
Haller; Ramart
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1922 , vol. 174, p. 1212
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II)
参考文献
Wenkert, Ernest; Ferreira, Tamis W.
Journal of the Chemical Society, Chemical Communications, 1982 , # 15 p. 840 - 841
参考文献
Martin,M.M.; Gleicher,G.J.
Journal of the American Chemical Society, 1964 , vol. 86, p. 238 - 241
反应条件
1: HCl / ethanol / 0.25 h / Heating
2: Na / ethane-1,2-diol
View Scheme
参考文献
Kirmse,W. et al.
Chemische Berichte, 1966 , vol. 99, p. 2579 - 2592
反应条件
copper(l) iodide; boron trifluoride diethyl etherate in diethyl ether
other Lewis acids, solvents; Product distribution;
参考文献
Yamamoto, Yoshinori; Yamamoto, Shinichi; Yatagai, Hidetaka; Maruyama, Kazuhiro
Journal of the American Chemical Society, 1980 , vol. 102, # 7 p. 2318 - 2325
反应条件
(i), (ii) POCl3, Py; Multistep reaction;
参考文献
Mazzocchi,P.H.; Lustig,R.S.
Journal of the American Chemical Society, 1975 , vol. 97, # 13 p. 3707 - 3713
反应条件
1: 93 percent / H2O2-urea
2: Heating
View Scheme
参考文献
Guo, Yushen; Jenks, William S.
Journal of Organic Chemistry, 1997 , vol. 62, # 4 p. 857 - 864
反应条件
1.1: triphenylphosphine; 1H-imidazole; bromine / dichloromethane / 27 h / 20 °C / |Inert atmosphere
2.1: potassium carbonate / acetone / 24 h / |Reflux; |Inert atmosphere
3.1: (NH4)6[Mo7O24]*4H2O; dihydrogen peroxide / methanol; water / 2.5 h / 0 - 20 °C / |Inert atmosphere
4.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C / |Inert atmosphere
4.2: 20 h / 20 °C / |Inert atmosphere
5.1: N,N,N',N,-tetramethylethylenediamine; iron (III) acetylacetonate; CPME / diethyl ether / 18 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Denmark, Scott E.; Cresswell, Alexander J.
Journal of Organic Chemistry, 2013 , vol. 78, # 24 p. 12593 - 12628
反应条件
1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C / |Inert atmosphere
1.2: 20 h / 20 °C / |Inert atmosphere
2.1: N,N,N',N,-tetramethylethylenediamine; iron (III) acetylacetonate; CPME / diethyl ether / 18 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Denmark, Scott E.; Cresswell, Alexander J.
Journal of Organic Chemistry, 2013 , vol. 78, # 24 p. 12593 - 12628
