3-甲基-1-苯基-2-丁烯合成路线 （共 98 条）
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane
T=19°C; 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Babin, D.; Fourneron, J. D.; Harwood, L. M.; Julia, M.
Tetrahedron, 1981 , vol. 37, p. 325 - 332
参考文献
Bernotas, Ronald C.; Adams, Ginette; Carr, Albert A.
Tetrahedron, 1996 , vol. 52, # 19 p. 6519 - 6526
参考文献
Klages
Chemische Berichte, 1896 , vol. 29, p. 2593
反应条件
(i) Ni(CO)4, benzene, (ii) /BRN= 1446140/, DMF; Multistep reaction;
参考文献
Sato,K. et al.
Journal of Organic Chemistry, 1972 , vol. 37, # 3 p. 462 - 466
反应条件
2: hydrogen bromide / dann Umsetzung des erhaltenen 2-Brom-2-methyl-butens-(3)
3: folgend Behandlung des Reaktionsprodukts mit verd. Salzsaeure
View Scheme
参考文献
Claisen
Journal fuer Praktische Chemie (Leipzig), 1922 , vol. <2> 105, p. 72
Chemische Berichte, 1925 , vol. 58, p. 279 Anm. 15
反应条件
1: (i) Zn, MeMgI, (ii) P2O5, (iii) aq. NaOH
2: (decomposition) / 239 - 290.4 °C
View Scheme
参考文献
Bigley,D.B.; Thurman,J.C.
Journal of the Chemical Society, 1965 , p. 6202 - 6205
参考文献
Pudowik; Schergina
Zhurnal Obshchei Khimii, 1957 , vol. 27, p. 2750,2753; engl. Ausg. S. 2789, 2791
参考文献
Nesmejanow et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1951 , p. 273,277
Chem.Abstr., 1952 , p. 882
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in tert-butyl alcohol
ΔGchem; Equilibrium constantThermodynamic data;
参考文献
Hine, Jack; Linden, Shwn-Meei
Journal of Organic Chemistry, 1983 , vol. 48, # 4 p. 584 - 587
参考文献
Guo, Yushen; Jenks, William S.
Journal of Organic Chemistry, 1997 , vol. 62, # 4 p. 857 - 864
