(1S,2S)-(-)-1-苯基亚丙基环氧合成路线 （共 41 条）
反应条件
molecular sieve; 2,6-dichloropyridine-N-oxide; [Ru(II)(D4-Por*)(CO)] in benzene T=20°C; 24 h; Title compound not separated from byproducts;
参考文献
Zhang, Jun-Long; Liu, Yun-Ling; Che, Chi-Ming
Chemical Communications, 2002 , # 23 p. 2906 - 2907
反应条件
sodium ethanolate in methanol T=0 - 20°C;
参考文献
Besse; Renard; Veschambre
Tetrahedron Asymmetry, 1994 , vol. 5, # 7 p. 1249 - 1268
反应条件
iodosylbenzene; iron(III) meso-tetraphenylporhinato chloride in toluene T=0°C; 2 h; Yield given. Yields of byproduct given;
参考文献
Groves, John T.; Viski, Peter
Journal of Organic Chemistry, 1990 , vol. 55, # 11 p. 3628 - 3634
反应条件
4-(tert-butyl)pyridine; Clorox bleach; tetradecyl benzyl dimethyl ammonium chloride; chiral manganese-porphyrin complex 6 in dichloromethane T=20°C; 4 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Halterman, Ronald L.; Jan, Shyi-Tai
Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5253 - 5254
反应条件
4-(tert-butyl)pyridine; Clorox bleach; tetradecyl benzyl dimethyl ammonium chloride; chiral manganese-porphyrin complex 6 in dichloromethane T=20°C; 4 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Finney, Nathaniel S.; Pospisil, Paul J.; Chang, Sukbok; Palucki, Michael; Konsler, Reed G.; Hansen, Karl B.; Jacobsen, Eric N.
Angewandte Chemie (International Edition in English), 1997 , vol. 36, # 16 p. 1720 - 1723
反应条件
(R,R)-[Cr(salen)] hexafluoroantimonate; 4 A molecular sieve; tert-butyl alcohol in various solvent(s) T=0°C; 36 h; Title compound not separated from byproducts;
参考文献
Bandini, Marco; Cozzi, Pier Giorgio; Melchiorre, Paolo; Umani-Ronchi, Achille
Angewandte Chemie - International Edition, 2004 , vol. 43, # 1 p. 84 - 87
反应条件
Oxonereg;; potassium carbonate; acetic acid; chiral 1a-methyl-3-fluoro-3-methyldecal-2-one in ethylene glycol dimethyl ether; water T=25°C; pH=8.5 - 9; 6 h; Title compound not separated from byproducts;
参考文献
Solladie-Cavallo, Arlette; Jierry, Loic; Klein, Arlette; Schmitt, Michel; Welter, Richard
Tetrahedron Asymmetry, 2004 , vol. 15, # 24 p. 3891 - 3898
反应条件
chiral ruthenium porphyrin complex catalyst in toluene T=-10°C; 48 h; Title compound not separated from byproducts.;
参考文献
Gross, Zeev; Ini, Santiago
Organic Letters, 1999 , vol. 1, # 13 p. 2077 - 2080
反应条件
pyridine; Oxonereg;; water-d2; sodium hydrogencarbonate; (S)-(-)-2-(diphenylmethyl)pyrrolidine in acetonitrile-D3 T=20°C; 4 h; Product distribution / selectivity;
参考文献
Bulman Page, Philip C.; Bartlett, Christopher J.; Chan, Yohan; Day, David; Parker, Phillip; Buckley, Benjamin R.; Rassias, Geracimos A.; Slawin, Alexandra M. Z.; Allin, Steven M.; Lacour, Jerome; Pinto, Andre
Journal of Organic Chemistry, 2012 , vol. 77, # 14 p. 6128 - 6138
反应条件
sodium hypochlorite; chiral (salen)Mn; (-)-N-benzylquininium chloride in chlorobenzene T=4°C; 10 h; other cis-olefins; other chiral quaternary ammonium salts; other Mn catalyst; other solvents; Product distribution;
参考文献
Chang, Sukbok; Galvin, Jennifer M.; Jacobsen, Eric N.
Journal of the American Chemical Society, 1994 , vol. 116, # 15 p. 6937 - 6938
