(1S,2S)-(-)-1-苯基亚丙基环氧合成路线 (共 41 条)
反应条件
1: K2CO3 / dioxane; H2O / Heating 2: E. coli JM109 (pTAB19) / 2,2,4-trimethyl-pentane / 30 °C View Scheme
参考文献
Sello, Guido; Orsini, Fulvia; Bernasconi, Silvana; Gennaro, Patrizia Di
Tetrahedron Asymmetry, 2006 , vol. 17, # 3 p. 372 - 376
反应条件
Agrocybe aegerita peroxygenase; dihydrogen peroxide in water; acetonitrile pH=7; 0.166667 h; potassium phosphate bufferEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Kluge, Martin; Ullrich, Rene; Scheibner, Katrin; Hofrichter, Martin
Green Chemistry, 2012 , vol. 14, # 2 p. 440 - 446
反应条件
1: 3-chloro-benzenecarboperoxoic acid 2: C68H92Cr2N8O4(2+)*2Cl(1-) / methanol; dichloromethane / 18 h / 20 °C View Scheme
参考文献
Kureshy, Rukhsana Ilays; Prathap, K. Jeya; Kumar, Manish; Bera, Prasanta Kumar; Khan, Noor-Ul Hasan; Abdi, Sayed Hasan Razi; Bajaj, Hari Chandra
Tetrahedron, 2011 , vol. 67, # 43 p. 8300 - 8307
反应条件
1: 3-chloro-benzenecarboperoxoic acid 2: C68H92Cr2N8O4(2+)*2Cl(1-) / methanol; dichloromethane / 30 h / 20 °C View Scheme
参考文献
Kureshy, Rukhsana Ilays; Prathap, K. Jeya; Kumar, Manish; Bera, Prasanta Kumar; Khan, Noor-Ul Hasan; Abdi, Sayed Hasan Razi; Bajaj, Hari Chandra
Tetrahedron, 2011 , vol. 67, # 43 p. 8300 - 8307
反应条件
1: 3-chloro-benzenecarboperoxoic acid 2: C68H92Cr2N8O4(2+)*2Cl(1-) / methanol; dichloromethane / 24 h / 20 °C View Scheme
参考文献
Kureshy, Rukhsana Ilays; Prathap, K. Jeya; Kumar, Manish; Bera, Prasanta Kumar; Khan, Noor-Ul Hasan; Abdi, Sayed Hasan Razi; Bajaj, Hari Chandra
Tetrahedron, 2011 , vol. 67, # 43 p. 8300 - 8307
反应条件
1: 3-chloro-benzenecarboperoxoic acid 2: C68H92Cr2N8O4(2+)*2Cl(1-) / methanol; dichloromethane / 20 h / 20 °C View Scheme
参考文献
Kureshy, Rukhsana Ilays; Prathap, K. Jeya; Kumar, Manish; Bera, Prasanta Kumar; Khan, Noor-Ul Hasan; Abdi, Sayed Hasan Razi; Bajaj, Hari Chandra
Tetrahedron, 2011 , vol. 67, # 43 p. 8300 - 8307
反应条件
1: 3-chloro-benzenecarboperoxoic acid 2: C68H92Cr2N8O4(2+)*2Cl(1-) / methanol; dichloromethane / 24 h / 20 °C View Scheme
参考文献
Kureshy, Rukhsana Ilays; Prathap, K. Jeya; Kumar, Manish; Bera, Prasanta Kumar; Khan, Noor-Ul Hasan; Abdi, Sayed Hasan Razi; Bajaj, Hari Chandra
Tetrahedron, 2011 , vol. 67, # 43 p. 8300 - 8307
反应条件
methanol; sodium methylate beim Behandeln des so erhaltenen <(1R,2S)-2-Hydroxy-1-methyl-2-phenyl-aethyl>-trimethyl-ammonium-jodids mit Silberoxid in Wasser;
参考文献
Fourneau; Benoit
Bulletin de la Societe Chimique de France, 1945 , vol. <5> 12, p. 985,988
反应条件
iodosylbenzene; Mn salen complex 2 in acetonitrile 12 h; Ambient temperature; Mechanism;
参考文献
Irie, Ryo; Noda, Keiko; Ito, Yoshio; Matsumoto, Naohide; Katsuki, Tsutomu
Tetrahedron Letters, 1990 , vol. 31, # 50 p. 7345 - 7348
反应条件
1: aq. H2SO4 2: (i) PBr5, CHCl3, (ii) Zn-Cu, aq. HCl View Scheme
参考文献
Fischer,F.
Chemische Berichte, 1961 , vol. 94, p. 893 - 901