1,4-双(三甲硅基)-1,3-丁二炔合成路线 （共 93 条）
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran T=25°C; Yields of byproduct given;
参考文献
Thorand; Krause
Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8551 - 8553
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran T=25°C; Yields of byproduct given;
参考文献
Thorand; Krause
Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8551 - 8553
反应条件
iron(III) chloride in tetrachloromethane; toluene T=25°C; 1.5 h;
参考文献
Bulletin de la Societe Chimique de France, , vol. 2, # 1-2 p. 16 - 20
反应条件
1: 2-butyn-1-al diethyl acetal With n-butyllithium; potassium tert-butylate in tetrahydrofuran; hexane T=-78 - -40°C; 2 h; 2: chloro-trimethyl-silane in tetrahydrofuran; hexane T=-78 - 20°C; 16 h; Further stages.;
参考文献
Blangetti, Marco; Deagostino, Annamaria; Rosso, Helena; Prandi, Cristina; Zavattaro, Chiara; Venturello, Paolo
European Journal of Organic Chemistry, 2007 , # 35 p. 5867 - 5874
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diisopropylamine in tetrahydrofuran T=20°C; Sonogashira coupling; 17 h; Inert atmosphere;
参考文献
Kloss, Florian; Koehn, Uwe; Jahn, Burkhard O.; Hager, Martin D.; Goerls, Helmar; Schubert, Ulrich S.
Chemistry - An Asian Journal, 2011 , vol. 6, # 10 p. 2816 - 2824
反应条件
n-butyllithium in tetrahydrofuran silylation;
参考文献
Solladie, Guy; Colobert, Francoise; Kalai, Chakib
Tetrahedron Letters, 2000 , vol. 41, # 21 p. 4197 - 4200
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) in triethylamine T=75°C; 480 h;
参考文献
European Journal of Inorganic Chemistry, , # 33 p. 5215 - 5225
反应条件
[PhCW{OSi(OtBu)3}3] in toluene T=20°C; 2 h; Molecular sieve;
参考文献
Lysenko, Sergej; Volbeda, Jeroen; Jones, Peter G.; Tamm, Matthias
Angewandte Chemie - International Edition, 2012 , vol. 51, # 27 p. 6757 - 6761
反应条件
air; N,N,N',N,-tetramethylethylenediamine; copper(l) chloride in acetone T=20°C; 2 h;
参考文献
Zhou, Ningzhang; Merschrod, Erika F. S.; Zhao, Yuming
Journal of the American Chemical Society, 2005 , vol. 127, # 41 p. 14154 - 14155
反应条件
copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride Sonogashira cross-coupling; cooling; Title compound not separated from byproducts;
参考文献
Macromolecules, , vol. 38, # 4 p. 1180 - 1189
