1,4-双(三甲硅基)-1,3-丁二炔合成路线 （共 93 条）
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine in toluene Sonogashira coupling; Inert atmosphere;
参考文献
Loerincz, Krisztian; Kele, Peter; Novak, Zoltan
Synthesis, 2009 , # 20 p. 3527 - 3532
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / -80 °C 1.2: 0.5 h / 0 °C 1.3: 16 h / 20 °C 2.1: [PhCW{OSi(OtBu)3}3] / toluene / 2 h / 20 °C / Molecular sieve View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 27 p. 6757 - 6761
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of the American Chemical Society, , vol. 112, # 4 p. 1607 - 1617
反应条件
in tetrahydrofuran byproducts: (CuBr)(n); under N2; soln. of CuBr2 in THF at 25°C mixed with equimolar amt. of Ti complex in THF; stirred at 25°C for 2 h; filtered through Kieselgur; volatiles removed in vac.; sepd. by chromy.(Kieselgel, -20°C, n-pentane);
参考文献
Journal of Organometallic Chemistry, , vol. 601, # 2 p. 226 - 232
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine 1.) THF, 25 deg C, 20 min, 2.) THF, 25 deg C, 16 h; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 63, # 23 p. 8551 - 8553
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine 1.) THF, 25 deg C, 20 min, 2.) THF, 25 deg C, 16 h; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 63, # 23 p. 8551 - 8553
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine 1.) THF, 25 deg C, 20 min, 2.) THF, 25 deg C, 16 h; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 63, # 23 p. 8551 - 8553
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine 1.) THF, 25 deg C, 20 min, 2.) THF, 25 deg C, 16 h; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 63, # 23 p. 8551 - 8553
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine 1.) THF, 25 deg C, 20 min, 2.) THF, 25 deg C, 16 h; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 63, # 23 p. 8551 - 8553
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine 1.) THF, 25 deg C, 20 min, 2.) THF, 25 deg C, 16 h; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 63, # 23 p. 8551 - 8553
