1,4-双(三甲硅基)-1,3-丁二炔合成路线 （共 93 条）
反应条件
pyridine; methyllithium; bromine; lithium bromide 1.) THF, ether, from 0 deg C to 25 deg C, 1.5 h, 2.) THF, ether, methylene chloride, -78 deg C, 15 h; Multistep reaction;
参考文献
Hoheisel, Tobias N.; Frauenrath, Holger
Organic Letters, 2008 , vol. 10, # 20 p. 4525 - 4528
参考文献
Dunogues,J. et al.
Journal of Organometallic Chemistry, 1975 , vol. 87, p. 169 - 181
反应条件
Yield givenMultistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Block, Eric; Birringer, Marc; He, Chunhong
Angewandte Chemie - International Edition, 1999 , vol. 38, # 11 p. 1604 - 1607
反应条件
Yield givenMultistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Block, Eric; Birringer, Marc; He, Chunhong
Angewandte Chemie - International Edition, 1999 , vol. 38, # 11 p. 1604 - 1607
反应条件
aluminium trichloride in dichloromethane T=-78°C; 2 h;
参考文献
Courtneidge, John L.; Davies, Alwyn G.; Gregory, Peter S.
Journal of the Chemical Society, Chemical Communications, 1986 , # 16 p. 1273 - 1275
反应条件
N-bromosuccinmide; silver nitrate in acetone T=20°C; 4 h;
参考文献
Liu, Pei-Hua; Li, Lei; Webb, Jeffrey A.; Zhang, Yi; Goroff, Nancy S.
Organic Letters, 2004 , vol. 6, # 13 p. 2081 - 2083
参考文献
Journal of Organometallic Chemistry, , vol. 545-546, p. 611 - 613
反应条件
NaOD; water-d2 in methanol-d4
参考文献
Maier, John P.; Marthaler, Oskar; Kloster-Jensen, Else
Journal of Chemical Physics, 1980 , vol. 72, # 1 p. 701 - 708
反应条件
aluminium trichloride in dichloromethane T=0°C; 5 h;
参考文献
Holmes, Andrew B.; Tabor, Alethea B.; Baker, Raymond
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 12 p. 3307 - 3313
反应条件
in dichloromethane; acetonitrile (N2); -10°C to room temp. (45 min); solvent removal, dissoln. (CH2Cl2), prep. TLC (SiO2; light petroleum/acetone);
参考文献
Bruce, Michael I.; Low, Paul J.; Werth, Anja; Skelton, Brian W.; White, Allan H.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 8 p. 1551 - 1566
