2,6-二(三氟甲基)吡啶合成路线 (共 5 条)
反应条件
1: (trifluoromethyl)-trimethylsilane With silver fluoride in N,N-dimethyl-formamide T=20°C; 0.333333 h; 2: With copper in N,N-dimethyl-formamide 4 h; 3: 2,6-Dibromopyridine in N,N-dimethyl-formamide T=75°C; 4 h;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Yagupolskii, Yurii L.; Naumann, Dieter; Moeller, Angela
Journal of Fluorine Chemistry, 2012 , vol. 133, p. 67 - 71
反应条件
F6Mo T=190 - 210°C; 45 h;
参考文献
Shustov, L. D.; Nikolenko, L. N.; Senchenkova, T. M.
J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 1 p. 103 - 105,85 - 86
反应条件
isobutyramide; copper T=100°C; 8 h;
参考文献
Clark, James H.; Denness, James E.; McClinton, Martin A.; Wynd, Andrew J.
Journal of Fluorine Chemistry, 1990 , vol. 50, # 3 p. 411 - 426
反应条件
hydrogen fluoride T=300°C;
参考文献
McBee et al.
Industrial and Engineering Chemistry, 39 <1947 389
反应条件
96 h; IrradiationThe yields, the kind of products depend on the time of the irrad. and/or the temp., and the mol. ratio. Other trifluorometh. agents investigated; Product distribution;
参考文献
Naumann,D.; Wilkes,B.
Journal of Fluorine Chemistry, 1985 , vol. 30, p. 73