1: zinc(II) iodide / dichloromethane / 2 h / 20 °C / Inert atmosphere 2: water; triethylamine / methanol / 20 °C / Inert atmosphere View Scheme
参考文献
Balmond, Edward I.; Coe, Diane M.; Galan, M. Carmen; McGarrigle, Eoghan M.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 36 p. 9152 - 9155
Uhlig, F.; Stadelmann, B.; Zechmann, A.; Lassacher, P.; Stueger, H.; Hengge, E.
Phosphorus, Sulfur and Silicon and the Related Elements, 1994 , vol. 90, # 1-4 p. 29 - 40
Shiner, Christopher S.; Tsunoda, Tetsuto; Goodman, Burton A.; Ingham, Stephen; Lee, Shi-hung; Vorndam, Paul E.
Journal of the American Chemical Society, 1989 , vol. 111, # 4 p. 1381 - 1392
in carbon disulfide
byproducts: S(SPh)3, P(SPh)3; P4S3I2 (0.63 mmol) added to stirred soln. of SiMe3(SPh) (2.47 mmol) at 20 °C; resulting soln. stirred (15 min); soln. evapd. (vac., 20 °C) to leave a mixt. of P4S3, S(SPh)3, and P(SPh3);
参考文献
Tattershall, Bruce W.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 1707 - 1712
trimethylsilyl trifluoromethanesulfonate in dichloromethane
T=-78°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
